Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)(4){4-CH(3)CO–C(6)H(4)-1-N(PPh(2))(2)}]

Chemical reactions of N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand (1) with three group 6B metal hexacarbonyls produced cis-M(CO)(4)[1-(k)(2)P,P][ M = Cr(2), Mo(3), W(4)], respectively. The novel complexes 2–4 were isolated and their structures were elucidated by multinuclear NMR spectroscop...

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Detalles Bibliográficos
Autores principales: Al-Masri, Harbi Tomah, Moussa, Ziad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2021
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8477991/
https://www.ncbi.nlm.nih.gov/pubmed/34611567
http://dx.doi.org/10.1016/j.heliyon.2021.e08050
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author Al-Masri, Harbi Tomah
Moussa, Ziad
author_facet Al-Masri, Harbi Tomah
Moussa, Ziad
author_sort Al-Masri, Harbi Tomah
collection PubMed
description Chemical reactions of N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand (1) with three group 6B metal hexacarbonyls produced cis-M(CO)(4)[1-(k)(2)P,P][ M = Cr(2), Mo(3), W(4)], respectively. The novel complexes 2–4 were isolated and their structures were elucidated by multinuclear NMR spectroscopy ((1)H, (13)C, (31)P NMR) and elemental analysis. Crystal-structure determination using single-crystal X-ray diffraction was carried out on complex 2.
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spelling pubmed-84779912021-10-04 Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)(4){4-CH(3)CO–C(6)H(4)-1-N(PPh(2))(2)}] Al-Masri, Harbi Tomah Moussa, Ziad Heliyon Research Article Chemical reactions of N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand (1) with three group 6B metal hexacarbonyls produced cis-M(CO)(4)[1-(k)(2)P,P][ M = Cr(2), Mo(3), W(4)], respectively. The novel complexes 2–4 were isolated and their structures were elucidated by multinuclear NMR spectroscopy ((1)H, (13)C, (31)P NMR) and elemental analysis. Crystal-structure determination using single-crystal X-ray diffraction was carried out on complex 2. Elsevier 2021-09-21 /pmc/articles/PMC8477991/ /pubmed/34611567 http://dx.doi.org/10.1016/j.heliyon.2021.e08050 Text en © 2021 The Authors https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Research Article
Al-Masri, Harbi Tomah
Moussa, Ziad
Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)(4){4-CH(3)CO–C(6)H(4)-1-N(PPh(2))(2)}]
title Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)(4){4-CH(3)CO–C(6)H(4)-1-N(PPh(2))(2)}]
title_full Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)(4){4-CH(3)CO–C(6)H(4)-1-N(PPh(2))(2)}]
title_fullStr Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)(4){4-CH(3)CO–C(6)H(4)-1-N(PPh(2))(2)}]
title_full_unstemmed Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)(4){4-CH(3)CO–C(6)H(4)-1-N(PPh(2))(2)}]
title_short Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)(4){4-CH(3)CO–C(6)H(4)-1-N(PPh(2))(2)}]
title_sort tetracarbonyl group 6b metal complexes of a n-(4-acetylphenyl)-n-(diphenylphosphino)amine ligand. molecular structure of cis-[cr(co)(4){4-ch(3)co–c(6)h(4)-1-n(pph(2))(2)}]
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8477991/
https://www.ncbi.nlm.nih.gov/pubmed/34611567
http://dx.doi.org/10.1016/j.heliyon.2021.e08050
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AT moussaziad tetracarbonylgroup6bmetalcomplexesofan4acetylphenylndiphenylphosphinoamineligandmolecularstructureofciscrco44ch3coc6h41npph22

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