Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst

The development of efficient heterogeneous catalysts for one-pot tandem/cascade synthesis of imines remains meaningful and challenging. Herein, we constructed an Au/MOF catalyst featured hollow and double MOF shell nanostructure. Owing to its structural merits and acid-basic nature, the as-synthesiz...

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Autores principales: Shi, Shunli, Yu, Ying, Zhang, Bingzhen, Zhong, Yicheng, Wang, Lei, Wang, Shuhua, Ding, Shunmin, Chen, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8479107/
https://www.ncbi.nlm.nih.gov/pubmed/34604171
http://dx.doi.org/10.3389/fchem.2021.738736
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author Shi, Shunli
Yu, Ying
Zhang, Bingzhen
Zhong, Yicheng
Wang, Lei
Wang, Shuhua
Ding, Shunmin
Chen, Chao
author_facet Shi, Shunli
Yu, Ying
Zhang, Bingzhen
Zhong, Yicheng
Wang, Lei
Wang, Shuhua
Ding, Shunmin
Chen, Chao
author_sort Shi, Shunli
collection PubMed
description The development of efficient heterogeneous catalysts for one-pot tandem/cascade synthesis of imines remains meaningful and challenging. Herein, we constructed an Au/MOF catalyst featured hollow and double MOF shell nanostructure. Owing to its structural merits and acid-basic nature, the as-synthesized Void|(Au)ZIF-8|ZIF-8 catalyst exhibited an enhanced synergistically catalytic performance for tandem catalytic synthesis of imines from benzyl alcohol and aniline under air atmosphere and solvent-free condition. Its 170.16 h(−1) of turnover frequency (TOF) was 2.5 times higher than that of the reported catalyst with the highest TOF value.
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spelling pubmed-84791072021-09-30 Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst Shi, Shunli Yu, Ying Zhang, Bingzhen Zhong, Yicheng Wang, Lei Wang, Shuhua Ding, Shunmin Chen, Chao Front Chem Chemistry The development of efficient heterogeneous catalysts for one-pot tandem/cascade synthesis of imines remains meaningful and challenging. Herein, we constructed an Au/MOF catalyst featured hollow and double MOF shell nanostructure. Owing to its structural merits and acid-basic nature, the as-synthesized Void|(Au)ZIF-8|ZIF-8 catalyst exhibited an enhanced synergistically catalytic performance for tandem catalytic synthesis of imines from benzyl alcohol and aniline under air atmosphere and solvent-free condition. Its 170.16 h(−1) of turnover frequency (TOF) was 2.5 times higher than that of the reported catalyst with the highest TOF value. Frontiers Media S.A. 2021-09-15 /pmc/articles/PMC8479107/ /pubmed/34604171 http://dx.doi.org/10.3389/fchem.2021.738736 Text en Copyright © 2021 Shi, Yu, Zhang, Zhong, Wang, Wang, Ding and Chen. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Shi, Shunli
Yu, Ying
Zhang, Bingzhen
Zhong, Yicheng
Wang, Lei
Wang, Shuhua
Ding, Shunmin
Chen, Chao
Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst
title Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst
title_full Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst
title_fullStr Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst
title_full_unstemmed Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst
title_short Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst
title_sort step by step construction of multifunctional hollow double shell mnps@mof as a powerful tandem/cascade catalyst
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8479107/
https://www.ncbi.nlm.nih.gov/pubmed/34604171
http://dx.doi.org/10.3389/fchem.2021.738736
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