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Manipulating Chemical Processes by Pseudosolid Spatial Limitation

[Image: see text] It is always preferred to perform chemical processes in liquid or gas phases because of the merits of operation convenience, reaction efficiency, and component homogeneity. However, tremendous efforts have to be made to purify the final product and minimize procedure losses unless...

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Autores principales: Yi, Shin, Chen, Jia-Syuan, Wang, Chang-Ming, Liao, Wei-Ssu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8479777/
https://www.ncbi.nlm.nih.gov/pubmed/34604853
http://dx.doi.org/10.1021/jacsau.1c00202
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author Yi, Shin
Chen, Jia-Syuan
Wang, Chang-Ming
Liao, Wei-Ssu
author_facet Yi, Shin
Chen, Jia-Syuan
Wang, Chang-Ming
Liao, Wei-Ssu
author_sort Yi, Shin
collection PubMed
description [Image: see text] It is always preferred to perform chemical processes in liquid or gas phases because of the merits of operation convenience, reaction efficiency, and component homogeneity. However, tremendous efforts have to be made to purify the final product and minimize procedure losses unless a well-defined chemical mechanism is found. Herein, an unconventional chemical functioning system accommodating molecule-in-pseudosolid manipulation is reported. It entails the properties of enhanced molecular effective collision and directional guidance for delicate chemical reaction spatial controls. This design achieves facilitated rates on multicomponent chemical reactions with pros of unique simultaneous final product separation through intrapseudosolid spatial limitation. Localized homogeneous component mixing, pronounced molecular collision, and pure product separation happening in this action surmount the obstacles of conventional chemical operation with a straightforward sketch. A path toward fine chemistry is therefore paved, where traditional thoughts on beneficial reaction environments may be reconsidered.
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spelling pubmed-84797772021-09-30 Manipulating Chemical Processes by Pseudosolid Spatial Limitation Yi, Shin Chen, Jia-Syuan Wang, Chang-Ming Liao, Wei-Ssu JACS Au [Image: see text] It is always preferred to perform chemical processes in liquid or gas phases because of the merits of operation convenience, reaction efficiency, and component homogeneity. However, tremendous efforts have to be made to purify the final product and minimize procedure losses unless a well-defined chemical mechanism is found. Herein, an unconventional chemical functioning system accommodating molecule-in-pseudosolid manipulation is reported. It entails the properties of enhanced molecular effective collision and directional guidance for delicate chemical reaction spatial controls. This design achieves facilitated rates on multicomponent chemical reactions with pros of unique simultaneous final product separation through intrapseudosolid spatial limitation. Localized homogeneous component mixing, pronounced molecular collision, and pure product separation happening in this action surmount the obstacles of conventional chemical operation with a straightforward sketch. A path toward fine chemistry is therefore paved, where traditional thoughts on beneficial reaction environments may be reconsidered. American Chemical Society 2021-08-03 /pmc/articles/PMC8479777/ /pubmed/34604853 http://dx.doi.org/10.1021/jacsau.1c00202 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Yi, Shin
Chen, Jia-Syuan
Wang, Chang-Ming
Liao, Wei-Ssu
Manipulating Chemical Processes by Pseudosolid Spatial Limitation
title Manipulating Chemical Processes by Pseudosolid Spatial Limitation
title_full Manipulating Chemical Processes by Pseudosolid Spatial Limitation
title_fullStr Manipulating Chemical Processes by Pseudosolid Spatial Limitation
title_full_unstemmed Manipulating Chemical Processes by Pseudosolid Spatial Limitation
title_short Manipulating Chemical Processes by Pseudosolid Spatial Limitation
title_sort manipulating chemical processes by pseudosolid spatial limitation
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8479777/
https://www.ncbi.nlm.nih.gov/pubmed/34604853
http://dx.doi.org/10.1021/jacsau.1c00202
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