Dipolar repulsion in α-halocarbonyl compounds revisited

The concept of dipolar repulsion has been widely used to explain several phenomena in organic chemistry, including the conformational preferences of carbonyl compounds. This model, in which atoms and bonds are viewed as point charges and dipole moment vectors, respectively, is however oversimplified...

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Detalles Bibliográficos
Autores principales: Rodrigues Silva, Daniela, de Azevedo Santos, Lucas, Hamlin, Trevor A., Bickelhaupt, F. Matthias, P. Freitas, Matheus, Fonseca Guerra, Célia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8479779/
https://www.ncbi.nlm.nih.gov/pubmed/34528039
http://dx.doi.org/10.1039/d1cp02502c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8479779/
https://www.ncbi.nlm.nih.gov/pubmed/34528039
http://dx.doi.org/10.1039/d1cp02502c

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