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Reactivity of [Pt(P(t)Bu(3))(2)] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity

[Image: see text] Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi cross-coupling reactions. Zinc-based ligands in bimetallic complexes also render unique reactivity to the transition metals at which they are bound. Here we exp...

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Detalles Bibliográficos
Autores principales: Hidalgo, Nereida, Romero-Pérez, Carlos, Maya, Celia, Fernández, Israel, Campos, Jesús
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8479860/
https://www.ncbi.nlm.nih.gov/pubmed/34602699
http://dx.doi.org/10.1021/acs.organomet.1c00088