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The power of trichlorosilylation: isolable trisilylated allyl anions, allyl radicals, and allenyl anions

Treatment of hexachloropropene (Cl(2)C[double bond, length as m-dash]C(Cl)–CCl(3)) with Si(2)Cl(6) and [nBu(4)N]Cl (1 : 4 : 1) in CH(2)Cl(2) results in a quantitative conversion to the trisilylated, dichlorinated allyl anion salt [nBu(4)N][Cl(2)C[double bond, length as m-dash]C(SiCl(3))–C(SiCl(3))(2...

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Detalles Bibliográficos
Autores principales:	Georg, Isabelle, Bursch, Markus, Endeward, Burkhard, Bolte, Michael, Lerner, Hans-Wolfram, Grimme, Stefan, Wagner, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8480423/ https://www.ncbi.nlm.nih.gov/pubmed/34603672 http://dx.doi.org/10.1039/d1sc03958j

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