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Fluorescence quenching based detection of nitroaromatics using luminescent triphenylamine carboxylic acids
Detection of nitroaromatics employing greener techniques has been one of the most active research fields in chemistry. A series of triphenylamine (TPA) functionalized carboxylic acids were synthesized and characterized using various spectroscopic techniques including single-crystal X-ray diffraction...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8481287/ https://www.ncbi.nlm.nih.gov/pubmed/34588466 http://dx.doi.org/10.1038/s41598-021-97832-0 |
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author | Mishra, Aamnayee Dheepika, R. Parvathy, P. A. Imran, P. M. Bhuvanesh, N. S. P. Nagarajan, S. |
author_facet | Mishra, Aamnayee Dheepika, R. Parvathy, P. A. Imran, P. M. Bhuvanesh, N. S. P. Nagarajan, S. |
author_sort | Mishra, Aamnayee |
collection | PubMed |
description | Detection of nitroaromatics employing greener techniques has been one of the most active research fields in chemistry. A series of triphenylamine (TPA) functionalized carboxylic acids were synthesized and characterized using various spectroscopic techniques including single-crystal X-ray diffraction analysis. The interaction of carboxylic acid-decorated TPAs with nitroaromatic compounds was photophysically explored using absorption and emission spectroscopy. Stern–Volmer plot accounts for the appreciable quenching constant of the TPA-acids. Density functional theory calculations were carried out to study the new compounds' frontier molecular orbital energy levels and the possible interactions with picrate anion and revealed an unusual charge transfer interaction between acids and picrate anion. The contact mode detection shows the TPA-acids can be used as dip-strip sensors for picric acid detection. |
format | Online Article Text |
id | pubmed-8481287 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-84812872021-09-30 Fluorescence quenching based detection of nitroaromatics using luminescent triphenylamine carboxylic acids Mishra, Aamnayee Dheepika, R. Parvathy, P. A. Imran, P. M. Bhuvanesh, N. S. P. Nagarajan, S. Sci Rep Article Detection of nitroaromatics employing greener techniques has been one of the most active research fields in chemistry. A series of triphenylamine (TPA) functionalized carboxylic acids were synthesized and characterized using various spectroscopic techniques including single-crystal X-ray diffraction analysis. The interaction of carboxylic acid-decorated TPAs with nitroaromatic compounds was photophysically explored using absorption and emission spectroscopy. Stern–Volmer plot accounts for the appreciable quenching constant of the TPA-acids. Density functional theory calculations were carried out to study the new compounds' frontier molecular orbital energy levels and the possible interactions with picrate anion and revealed an unusual charge transfer interaction between acids and picrate anion. The contact mode detection shows the TPA-acids can be used as dip-strip sensors for picric acid detection. Nature Publishing Group UK 2021-09-29 /pmc/articles/PMC8481287/ /pubmed/34588466 http://dx.doi.org/10.1038/s41598-021-97832-0 Text en © The Author(s) 2021 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Article Mishra, Aamnayee Dheepika, R. Parvathy, P. A. Imran, P. M. Bhuvanesh, N. S. P. Nagarajan, S. Fluorescence quenching based detection of nitroaromatics using luminescent triphenylamine carboxylic acids |
title | Fluorescence quenching based detection of nitroaromatics using luminescent triphenylamine carboxylic acids |
title_full | Fluorescence quenching based detection of nitroaromatics using luminescent triphenylamine carboxylic acids |
title_fullStr | Fluorescence quenching based detection of nitroaromatics using luminescent triphenylamine carboxylic acids |
title_full_unstemmed | Fluorescence quenching based detection of nitroaromatics using luminescent triphenylamine carboxylic acids |
title_short | Fluorescence quenching based detection of nitroaromatics using luminescent triphenylamine carboxylic acids |
title_sort | fluorescence quenching based detection of nitroaromatics using luminescent triphenylamine carboxylic acids |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8481287/ https://www.ncbi.nlm.nih.gov/pubmed/34588466 http://dx.doi.org/10.1038/s41598-021-97832-0 |
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