Terminal Terthiophenediones: Fast-Decay Fluorescent Dyes and Their Efficient Syntheses

[Image: see text] Terminally acylated terthiophenes, in particular, the bis-pivaloyl derivative, were synthesized by Friedel–Crafts acylation with sub-stoichiometric amounts of standard zinc oxide and exhibit strong fluorescence and an ultrafast fluorescence decay of 400 ps. Their high photostabilit...

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Autores principales: Langhals, Heinz, Schlücker, Thorben, Reiners, Felix, Karaghiosoff, Konstantin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8482468/
https://www.ncbi.nlm.nih.gov/pubmed/34604678
http://dx.doi.org/10.1021/acsomega.1c04010
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author Langhals, Heinz
Schlücker, Thorben
Reiners, Felix
Karaghiosoff, Konstantin
author_facet Langhals, Heinz
Schlücker, Thorben
Reiners, Felix
Karaghiosoff, Konstantin
author_sort Langhals, Heinz
collection PubMed
description [Image: see text] Terminally acylated terthiophenes, in particular, the bis-pivaloyl derivative, were synthesized by Friedel–Crafts acylation with sub-stoichiometric amounts of standard zinc oxide and exhibit strong fluorescence and an ultrafast fluorescence decay of 400 ps. Their high photostability and large Stokes’ shifts are good prerequisites for applications in optical GBit fast data systems such as fiber optics in slip rings.
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spelling pubmed-84824682021-10-01 Terminal Terthiophenediones: Fast-Decay Fluorescent Dyes and Their Efficient Syntheses Langhals, Heinz Schlücker, Thorben Reiners, Felix Karaghiosoff, Konstantin ACS Omega [Image: see text] Terminally acylated terthiophenes, in particular, the bis-pivaloyl derivative, were synthesized by Friedel–Crafts acylation with sub-stoichiometric amounts of standard zinc oxide and exhibit strong fluorescence and an ultrafast fluorescence decay of 400 ps. Their high photostability and large Stokes’ shifts are good prerequisites for applications in optical GBit fast data systems such as fiber optics in slip rings. American Chemical Society 2021-09-14 /pmc/articles/PMC8482468/ /pubmed/34604678 http://dx.doi.org/10.1021/acsomega.1c04010 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Langhals, Heinz
Schlücker, Thorben
Reiners, Felix
Karaghiosoff, Konstantin
Terminal Terthiophenediones: Fast-Decay Fluorescent Dyes and Their Efficient Syntheses
title Terminal Terthiophenediones: Fast-Decay Fluorescent Dyes and Their Efficient Syntheses
title_full Terminal Terthiophenediones: Fast-Decay Fluorescent Dyes and Their Efficient Syntheses
title_fullStr Terminal Terthiophenediones: Fast-Decay Fluorescent Dyes and Their Efficient Syntheses
title_full_unstemmed Terminal Terthiophenediones: Fast-Decay Fluorescent Dyes and Their Efficient Syntheses
title_short Terminal Terthiophenediones: Fast-Decay Fluorescent Dyes and Their Efficient Syntheses
title_sort terminal terthiophenediones: fast-decay fluorescent dyes and their efficient syntheses
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8482468/
https://www.ncbi.nlm.nih.gov/pubmed/34604678
http://dx.doi.org/10.1021/acsomega.1c04010
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