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Complex Polyheterocycles and the Stereochemical Reassignment of Pileamartine A via Aza-Heck Triggered Aryl C–H Functionalization Cascades

[Image: see text] Structurally complex benzo- and spiro-fused N-polyheterocycles can be accessed via intramolecular Pd(0)-catalyzed alkene 1,2-aminoarylation reactions. The method uses N-(pentafluorobenzoyloxy)carbamates as the initiating motif, and this allows aza-Heck-type alkene amino-palladation...

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Detalles Bibliográficos
Autores principales:	Jones, Benjamin T., García-Cárceles, Javier, Caiger, Lewis, Hazelden, Ian R., Lewis, Richard J., Langer, Thomas, Bower, John F.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8485351/ https://www.ncbi.nlm.nih.gov/pubmed/34546043 http://dx.doi.org/10.1021/jacs.1c08615

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