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Enantioselective Inverse-Electron Demand Aza-Diels–Alder Reaction: ipso,α-Selectivity of Silyl Dienol Ethers

[Image: see text] A highly efficient enantioselective inverse-electron-demand aza-Diels–Alder reaction between aza-sulfonyl-1-aza-1,3-butadienes and silyl (di)enol ethers has been developed. The presented methodology allows the synthesis of benzofuran-fused 2-piperidinol derivatives with three conti...

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Detalles Bibliográficos
Autores principales: Laina-Martín, Víctor, Humbrías-Martín, Jorge, Mas-Ballesté, Rubén, Fernández-Salas, Jose A., Alemán, José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491166/
https://www.ncbi.nlm.nih.gov/pubmed/34621594
http://dx.doi.org/10.1021/acscatal.1c03390