Crystal structure and Hirshfeld surface analysis of 2,2,2-tri­chloro-N,N-bis­{[(1RS,4SR)-1,4-di­hydro-1,4-ep­oxy­naphthalen-1-yl]meth­yl}acetamide

In the title compound, C(24)H(18)Cl(3)NO(3), the tetra­hydro­furan rings adopt envelope conformations. In the crystal, C—H⋯O hydrogen bonds connect mol­ecules, generating layers parallel to the (001) plane. These layers are connected along the c-axis direction by C—H⋯π inter­actions. The packing is...

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Autores principales: Atioğlu, Zeliha, Akkurt, Mehmet, Mammadova, Gunay Z., Bhattarai, Ajaya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491519/
https://www.ncbi.nlm.nih.gov/pubmed/34667636
http://dx.doi.org/10.1107/S2056989021009907
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author Atioğlu, Zeliha
Akkurt, Mehmet
Mammadova, Gunay Z.
Bhattarai, Ajaya
author_facet Atioğlu, Zeliha
Akkurt, Mehmet
Mammadova, Gunay Z.
Bhattarai, Ajaya
author_sort Atioğlu, Zeliha
collection PubMed
description In the title compound, C(24)H(18)Cl(3)NO(3), the tetra­hydro­furan rings adopt envelope conformations. In the crystal, C—H⋯O hydrogen bonds connect mol­ecules, generating layers parallel to the (001) plane. These layers are connected along the c-axis direction by C—H⋯π inter­actions. The packing is further stabilized by inter­layer van der Waals and inter­halogen inter­actions. The most important contributions to the surface contacts are from H⋯H (36.8%), Cl⋯H/H⋯Cl (26.6%), C⋯H/H⋯C (18.8%) and O⋯H/H⋯O (11.3%) inter­actions, as concluded from a Hirshfeld surface analysis.
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spelling pubmed-84915192021-10-18 Crystal structure and Hirshfeld surface analysis of 2,2,2-tri­chloro-N,N-bis­{[(1RS,4SR)-1,4-di­hydro-1,4-ep­oxy­naphthalen-1-yl]meth­yl}acetamide Atioğlu, Zeliha Akkurt, Mehmet Mammadova, Gunay Z. Bhattarai, Ajaya Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(24)H(18)Cl(3)NO(3), the tetra­hydro­furan rings adopt envelope conformations. In the crystal, C—H⋯O hydrogen bonds connect mol­ecules, generating layers parallel to the (001) plane. These layers are connected along the c-axis direction by C—H⋯π inter­actions. The packing is further stabilized by inter­layer van der Waals and inter­halogen inter­actions. The most important contributions to the surface contacts are from H⋯H (36.8%), Cl⋯H/H⋯Cl (26.6%), C⋯H/H⋯C (18.8%) and O⋯H/H⋯O (11.3%) inter­actions, as concluded from a Hirshfeld surface analysis. International Union of Crystallography 2021-09-28 /pmc/articles/PMC8491519/ /pubmed/34667636 http://dx.doi.org/10.1107/S2056989021009907 Text en © Atioğlu et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Atioğlu, Zeliha
Akkurt, Mehmet
Mammadova, Gunay Z.
Bhattarai, Ajaya
Crystal structure and Hirshfeld surface analysis of 2,2,2-tri­chloro-N,N-bis­{[(1RS,4SR)-1,4-di­hydro-1,4-ep­oxy­naphthalen-1-yl]meth­yl}acetamide
title Crystal structure and Hirshfeld surface analysis of 2,2,2-tri­chloro-N,N-bis­{[(1RS,4SR)-1,4-di­hydro-1,4-ep­oxy­naphthalen-1-yl]meth­yl}acetamide
title_full Crystal structure and Hirshfeld surface analysis of 2,2,2-tri­chloro-N,N-bis­{[(1RS,4SR)-1,4-di­hydro-1,4-ep­oxy­naphthalen-1-yl]meth­yl}acetamide
title_fullStr Crystal structure and Hirshfeld surface analysis of 2,2,2-tri­chloro-N,N-bis­{[(1RS,4SR)-1,4-di­hydro-1,4-ep­oxy­naphthalen-1-yl]meth­yl}acetamide
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of 2,2,2-tri­chloro-N,N-bis­{[(1RS,4SR)-1,4-di­hydro-1,4-ep­oxy­naphthalen-1-yl]meth­yl}acetamide
title_short Crystal structure and Hirshfeld surface analysis of 2,2,2-tri­chloro-N,N-bis­{[(1RS,4SR)-1,4-di­hydro-1,4-ep­oxy­naphthalen-1-yl]meth­yl}acetamide
title_sort crystal structure and hirshfeld surface analysis of 2,2,2-tri­chloro-n,n-bis­{[(1rs,4sr)-1,4-di­hydro-1,4-ep­oxy­naphthalen-1-yl]meth­yl}acetamide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491519/
https://www.ncbi.nlm.nih.gov/pubmed/34667636
http://dx.doi.org/10.1107/S2056989021009907
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