Crystal structure and Hirshfeld surface analysis of (E)-4-({2,2-di­chloro-1-[4-(di­methyl­amino)­phen­yl]ethenyl}diazen­yl)benzo­nitrile

In the title compound, C(17)H(14)Cl(2)N(4), the dihedral angle between the aromatic rings is 50.09 (9)°. The central –N=N– unit shows an E configuration. In the crystal, C—H⋯N inter­actions, C—Cl⋯π and π–π stacking inter­actions [centroid-to-centroid distance = 3.7719 (14) Å] link the mol­ecules, fo...

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Autores principales: Shikhaliyev, Namiq Q., Atioğlu, Zeliha, Akkurt, Mehmet, Suleymanova, Gulnar T., Babayeva, Gulnare V., Mlowe, Sixberth
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491520/
https://www.ncbi.nlm.nih.gov/pubmed/34667625
http://dx.doi.org/10.1107/S2056989021009154
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author Shikhaliyev, Namiq Q.
Atioğlu, Zeliha
Akkurt, Mehmet
Suleymanova, Gulnar T.
Babayeva, Gulnare V.
Mlowe, Sixberth
author_facet Shikhaliyev, Namiq Q.
Atioğlu, Zeliha
Akkurt, Mehmet
Suleymanova, Gulnar T.
Babayeva, Gulnare V.
Mlowe, Sixberth
author_sort Shikhaliyev, Namiq Q.
collection PubMed
description In the title compound, C(17)H(14)Cl(2)N(4), the dihedral angle between the aromatic rings is 50.09 (9)°. The central –N=N– unit shows an E configuration. In the crystal, C—H⋯N inter­actions, C—Cl⋯π and π–π stacking inter­actions [centroid-to-centroid distance = 3.7719 (14) Å] link the mol­ecules, forming mol­ecular layers approximately parallel to the (002) plane. Additional weak van der Waals inter­actions between the layers consolidate the three-dimensional packing. Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (33.6%), N⋯H/ H⋯N (17.2%), Cl⋯H/H⋯Cl (14.1%) and C⋯H/H⋯C (14.1%) contacts.
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spelling pubmed-84915202021-10-18 Crystal structure and Hirshfeld surface analysis of (E)-4-({2,2-di­chloro-1-[4-(di­methyl­amino)­phen­yl]ethenyl}diazen­yl)benzo­nitrile Shikhaliyev, Namiq Q. Atioğlu, Zeliha Akkurt, Mehmet Suleymanova, Gulnar T. Babayeva, Gulnare V. Mlowe, Sixberth Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(17)H(14)Cl(2)N(4), the dihedral angle between the aromatic rings is 50.09 (9)°. The central –N=N– unit shows an E configuration. In the crystal, C—H⋯N inter­actions, C—Cl⋯π and π–π stacking inter­actions [centroid-to-centroid distance = 3.7719 (14) Å] link the mol­ecules, forming mol­ecular layers approximately parallel to the (002) plane. Additional weak van der Waals inter­actions between the layers consolidate the three-dimensional packing. Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (33.6%), N⋯H/ H⋯N (17.2%), Cl⋯H/H⋯Cl (14.1%) and C⋯H/H⋯C (14.1%) contacts. International Union of Crystallography 2021-09-07 /pmc/articles/PMC8491520/ /pubmed/34667625 http://dx.doi.org/10.1107/S2056989021009154 Text en © Shikhaliyev et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shikhaliyev, Namiq Q.
Atioğlu, Zeliha
Akkurt, Mehmet
Suleymanova, Gulnar T.
Babayeva, Gulnare V.
Mlowe, Sixberth
Crystal structure and Hirshfeld surface analysis of (E)-4-({2,2-di­chloro-1-[4-(di­methyl­amino)­phen­yl]ethenyl}diazen­yl)benzo­nitrile
title Crystal structure and Hirshfeld surface analysis of (E)-4-({2,2-di­chloro-1-[4-(di­methyl­amino)­phen­yl]ethenyl}diazen­yl)benzo­nitrile
title_full Crystal structure and Hirshfeld surface analysis of (E)-4-({2,2-di­chloro-1-[4-(di­methyl­amino)­phen­yl]ethenyl}diazen­yl)benzo­nitrile
title_fullStr Crystal structure and Hirshfeld surface analysis of (E)-4-({2,2-di­chloro-1-[4-(di­methyl­amino)­phen­yl]ethenyl}diazen­yl)benzo­nitrile
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of (E)-4-({2,2-di­chloro-1-[4-(di­methyl­amino)­phen­yl]ethenyl}diazen­yl)benzo­nitrile
title_short Crystal structure and Hirshfeld surface analysis of (E)-4-({2,2-di­chloro-1-[4-(di­methyl­amino)­phen­yl]ethenyl}diazen­yl)benzo­nitrile
title_sort crystal structure and hirshfeld surface analysis of (e)-4-({2,2-di­chloro-1-[4-(di­methyl­amino)­phen­yl]ethenyl}diazen­yl)benzo­nitrile
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491520/
https://www.ncbi.nlm.nih.gov/pubmed/34667625
http://dx.doi.org/10.1107/S2056989021009154
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