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Crystal structure of [Th(3)(Cp*)(3)(O)(OH)(3)](2)Cl(2)(N(3))(6): a discrete molecular capsule built from multinuclear organothorium cluster cations
An unusually large and structurally complex charge-neutral polynuclear cluster, hexa-μ(2)-azido-di-μ(3)-chlorido-hexa-μ(2)-hydroxido-di-μ(3)-oxido-hexakis(pentamethylcyclopentadienyl)hexathorium–diethyl ether–tetrahydrofuran (1/0.56/1.44), [Th(3)(C(10)H(15))(6)Cl(3)(N(3))(6)(OH)(6)O(2)]·0....
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491527/ https://www.ncbi.nlm.nih.gov/pubmed/34667621 http://dx.doi.org/10.1107/S2056989021008914 |
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author | Kelley, Steven P. Rungthanaphatsophon, Pokpong Walensky, Justin R. |
author_facet | Kelley, Steven P. Rungthanaphatsophon, Pokpong Walensky, Justin R. |
author_sort | Kelley, Steven P. |
collection | PubMed |
description | An unusually large and structurally complex charge-neutral polynuclear cluster, hexa-μ(2)-azido-di-μ(3)-chlorido-hexa-μ(2)-hydroxido-di-μ(3)-oxido-hexakis(pentamethylcyclopentadienyl)hexathorium–diethyl ether–tetrahydrofuran (1/0.56/1.44), [Th(3)(C(10)H(15))(6)Cl(3)(N(3))(6)(OH)(6)O(2)]·0.56C(4)H(10)O·1.44C(4)H(8)O or [Th(3)(Cp*)(3)(O)(OH)(3)](2)Cl(2)(N(3))(6)·0.56C(4)H(10)O·1.44C(4)H(8)O (Cp* = [pentamethylcyclopentadienyl])(−), has been crystallized as a mixed tetrahydrofuran/diethyl ether solvate and structurally characterized. The molecule contains a number of unusual features, the most notable being a finite yet exceptionally long cyclic metal-azido chain. These rare features are the consequence of both sterically protecting Cp* ligands and highly bridging oxide and hydroxide ligands in the same system and illustrate the interesting new possibilities that can arise from combining organometallic and solvothermal f-block element chemistry. |
format | Online Article Text |
id | pubmed-8491527 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-84915272021-10-18 Crystal structure of [Th(3)(Cp*)(3)(O)(OH)(3)](2)Cl(2)(N(3))(6): a discrete molecular capsule built from multinuclear organothorium cluster cations Kelley, Steven P. Rungthanaphatsophon, Pokpong Walensky, Justin R. Acta Crystallogr E Crystallogr Commun Jerry P. Jasinski tribute An unusually large and structurally complex charge-neutral polynuclear cluster, hexa-μ(2)-azido-di-μ(3)-chlorido-hexa-μ(2)-hydroxido-di-μ(3)-oxido-hexakis(pentamethylcyclopentadienyl)hexathorium–diethyl ether–tetrahydrofuran (1/0.56/1.44), [Th(3)(C(10)H(15))(6)Cl(3)(N(3))(6)(OH)(6)O(2)]·0.56C(4)H(10)O·1.44C(4)H(8)O or [Th(3)(Cp*)(3)(O)(OH)(3)](2)Cl(2)(N(3))(6)·0.56C(4)H(10)O·1.44C(4)H(8)O (Cp* = [pentamethylcyclopentadienyl])(−), has been crystallized as a mixed tetrahydrofuran/diethyl ether solvate and structurally characterized. The molecule contains a number of unusual features, the most notable being a finite yet exceptionally long cyclic metal-azido chain. These rare features are the consequence of both sterically protecting Cp* ligands and highly bridging oxide and hydroxide ligands in the same system and illustrate the interesting new possibilities that can arise from combining organometallic and solvothermal f-block element chemistry. International Union of Crystallography 2021-09-03 /pmc/articles/PMC8491527/ /pubmed/34667621 http://dx.doi.org/10.1107/S2056989021008914 Text en © Kelley et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Jerry P. Jasinski tribute Kelley, Steven P. Rungthanaphatsophon, Pokpong Walensky, Justin R. Crystal structure of [Th(3)(Cp*)(3)(O)(OH)(3)](2)Cl(2)(N(3))(6): a discrete molecular capsule built from multinuclear organothorium cluster cations |
title | Crystal structure of [Th(3)(Cp*)(3)(O)(OH)(3)](2)Cl(2)(N(3))(6): a discrete molecular capsule built from multinuclear organothorium cluster cations |
title_full | Crystal structure of [Th(3)(Cp*)(3)(O)(OH)(3)](2)Cl(2)(N(3))(6): a discrete molecular capsule built from multinuclear organothorium cluster cations |
title_fullStr | Crystal structure of [Th(3)(Cp*)(3)(O)(OH)(3)](2)Cl(2)(N(3))(6): a discrete molecular capsule built from multinuclear organothorium cluster cations |
title_full_unstemmed | Crystal structure of [Th(3)(Cp*)(3)(O)(OH)(3)](2)Cl(2)(N(3))(6): a discrete molecular capsule built from multinuclear organothorium cluster cations |
title_short | Crystal structure of [Th(3)(Cp*)(3)(O)(OH)(3)](2)Cl(2)(N(3))(6): a discrete molecular capsule built from multinuclear organothorium cluster cations |
title_sort | crystal structure of [th(3)(cp*)(3)(o)(oh)(3)](2)cl(2)(n(3))(6): a discrete molecular capsule built from multinuclear organothorium cluster cations |
topic | Jerry P. Jasinski tribute |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491527/ https://www.ncbi.nlm.nih.gov/pubmed/34667621 http://dx.doi.org/10.1107/S2056989021008914 |
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