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Crystal structure of 9,9-diethyl-9H-fluorene-2,4,7-tricarbaldehyde
The title compound, C(20)H(18)O(3), crystallizes in the space group P2(1)/c with one molecule in the asymmetric unit of the cell. The fluorene skeleton is nearly planar and the crystal structure is composed of molecular layers extending parallel to the (302) plane. Within a layer, one formyl oxyge...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491529/ https://www.ncbi.nlm.nih.gov/pubmed/34667632 http://dx.doi.org/10.1107/S2056989021009464 |
Sumario: | The title compound, C(20)H(18)O(3), crystallizes in the space group P2(1)/c with one molecule in the asymmetric unit of the cell. The fluorene skeleton is nearly planar and the crystal structure is composed of molecular layers extending parallel to the (302) plane. Within a layer, one formyl oxygen atom participates in the formation of a C(arene)—H⋯O bond, which is responsible for the formation of an inversion symmetric supramolecular motif of graph set R (2) (2)(10). A second oxygen atom is involved in an intramolecular C(arene)—H⋯O hydrogen bond and is further connected with a formyl hydrogen atom of an adjacent molecule. A Hirshfeld surface analysis indicated that the most important contributions to the overall surface are from H⋯H (46.9%), O⋯H (27.9%) and C⋯H (17.8%) interactions. |
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