Crystal structure of caesium tetra­methyl­dithio­imidodiphosphinate

In the title crystal, the salt [CsMe(2)P(S)NP(S)Me(2)] is self-assembled as an undulating supra­molecular two-dimensional polymeric structure, poly[(μ(4)-tetra­methyl­dithio­imidodiphosphinato)caesium], [Cs(C(4)H(12)NP(2)S(2))](n), which is parallel to the bc plane. The Cs cations are hexa­coordinat...

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Detalles Bibliográficos
Autores principales: López-Cardoso, Marcela, Tlahuext, Hugo, Jancik, Vojtech, Cea-Olivares, Raymundo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491530/
https://www.ncbi.nlm.nih.gov/pubmed/34667638
http://dx.doi.org/10.1107/S2056989021009798
Descripción
Sumario:In the title crystal, the salt [CsMe(2)P(S)NP(S)Me(2)] is self-assembled as an undulating supra­molecular two-dimensional polymeric structure, poly[(μ(4)-tetra­methyl­dithio­imidodiphosphinato)caesium], [Cs(C(4)H(12)NP(2)S(2))](n), which is parallel to the bc plane. The Cs cations are hexa­coordinated, being chelated by two thio­imidophosphinate groups and two sulfur atoms from neighboring ligands. The anions are linked to the Cs cations by Cs⋯S and Cs⋯N electrostatic inter­actions.

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