Crystal structure of caesium tetra­methyl­dithio­imidodiphosphinate

In the title crystal, the salt [CsMe(2)P(S)NP(S)Me(2)] is self-assembled as an undulating supra­molecular two-dimensional polymeric structure, poly[(μ(4)-tetra­methyl­dithio­imidodiphosphinato)caesium], [Cs(C(4)H(12)NP(2)S(2))](n), which is parallel to the bc plane. The Cs cations are hexa­coordinat...

Descripción completa

Detalles Bibliográficos
Autores principales: López-Cardoso, Marcela, Tlahuext, Hugo, Jancik, Vojtech, Cea-Olivares, Raymundo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491530/
https://www.ncbi.nlm.nih.gov/pubmed/34667638
http://dx.doi.org/10.1107/S2056989021009798
_version_ 1784578750812258304
author López-Cardoso, Marcela
Tlahuext, Hugo
Jancik, Vojtech
Cea-Olivares, Raymundo
author_facet López-Cardoso, Marcela
Tlahuext, Hugo
Jancik, Vojtech
Cea-Olivares, Raymundo
author_sort López-Cardoso, Marcela
collection PubMed
description In the title crystal, the salt [CsMe(2)P(S)NP(S)Me(2)] is self-assembled as an undulating supra­molecular two-dimensional polymeric structure, poly[(μ(4)-tetra­methyl­dithio­imidodiphosphinato)caesium], [Cs(C(4)H(12)NP(2)S(2))](n), which is parallel to the bc plane. The Cs cations are hexa­coordinated, being chelated by two thio­imidophosphinate groups and two sulfur atoms from neighboring ligands. The anions are linked to the Cs cations by Cs⋯S and Cs⋯N electrostatic inter­actions.
format Online
Article
Text
id pubmed-8491530
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-84915302021-10-18 Crystal structure of caesium tetra­methyl­dithio­imidodiphosphinate López-Cardoso, Marcela Tlahuext, Hugo Jancik, Vojtech Cea-Olivares, Raymundo Acta Crystallogr E Crystallogr Commun Research Communications In the title crystal, the salt [CsMe(2)P(S)NP(S)Me(2)] is self-assembled as an undulating supra­molecular two-dimensional polymeric structure, poly[(μ(4)-tetra­methyl­dithio­imidodiphosphinato)caesium], [Cs(C(4)H(12)NP(2)S(2))](n), which is parallel to the bc plane. The Cs cations are hexa­coordinated, being chelated by two thio­imidophosphinate groups and two sulfur atoms from neighboring ligands. The anions are linked to the Cs cations by Cs⋯S and Cs⋯N electrostatic inter­actions. International Union of Crystallography 2021-09-30 /pmc/articles/PMC8491530/ /pubmed/34667638 http://dx.doi.org/10.1107/S2056989021009798 Text en © López-Cardoso et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
López-Cardoso, Marcela
Tlahuext, Hugo
Jancik, Vojtech
Cea-Olivares, Raymundo
Crystal structure of caesium tetra­methyl­dithio­imidodiphosphinate
title Crystal structure of caesium tetra­methyl­dithio­imidodiphosphinate
title_full Crystal structure of caesium tetra­methyl­dithio­imidodiphosphinate
title_fullStr Crystal structure of caesium tetra­methyl­dithio­imidodiphosphinate
title_full_unstemmed Crystal structure of caesium tetra­methyl­dithio­imidodiphosphinate
title_short Crystal structure of caesium tetra­methyl­dithio­imidodiphosphinate
title_sort crystal structure of caesium tetra­methyl­dithio­imidodiphosphinate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491530/
https://www.ncbi.nlm.nih.gov/pubmed/34667638
http://dx.doi.org/10.1107/S2056989021009798
work_keys_str_mv AT lopezcardosomarcela crystalstructureofcaesiumtetramethyldithioimidodiphosphinate
AT tlahuexthugo crystalstructureofcaesiumtetramethyldithioimidodiphosphinate
AT jancikvojtech crystalstructureofcaesiumtetramethyldithioimidodiphosphinate
AT ceaolivaresraymundo crystalstructureofcaesiumtetramethyldithioimidodiphosphinate

Ejemplares similares