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Sepiolite Nanocarriers as a Matrix for Controlled Thermal Energy Storage
[Image: see text] Applying the eutectic hydrated salt (EHS) mixture of Na(2)HPO(4)·12H(2)O and Na(2)SO(4)·10H(2)O in a 1:1 weight ratio as a phase-change material and natural sepiolite nanocarriers as a matrix, the form-stable phase-change composite EHS@sepiolite was fabricated by vacuum impregnatio...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8495839/ https://www.ncbi.nlm.nih.gov/pubmed/34632238 http://dx.doi.org/10.1021/acsomega.1c04392 |
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author | Zhu, Xiaolei Vinokurov, Vladimir Kopitsyn, Dmitry Shchukin, Dmitry G. |
author_facet | Zhu, Xiaolei Vinokurov, Vladimir Kopitsyn, Dmitry Shchukin, Dmitry G. |
author_sort | Zhu, Xiaolei |
collection | PubMed |
description | [Image: see text] Applying the eutectic hydrated salt (EHS) mixture of Na(2)HPO(4)·12H(2)O and Na(2)SO(4)·10H(2)O in a 1:1 weight ratio as a phase-change material and natural sepiolite nanocarriers as a matrix, the form-stable phase-change composite EHS@sepiolite was fabricated by vacuum impregnation. Due to the high porosity of sepiolite and its nanofibrous structure with internal channels, the effective loading of the phase-change material reached as high as 88 wt %. The melting temperature of the composite was 38.1 °C and its melting enthalpy was 185 J g(–1.) The crystallinity of the hydrated salt mixture was retained after loading into the sepiolite matrix. The composite demonstrated high stability over 50 heat uptake/release cycles maintaining its melting temperature and melting enthalpy the same. The combination of natural sepiolite nanocarriers and crystallohydrates is a cheap and efficient nanoscale energy storage system with high potential for practical applications and upscaling because of their natural abundance. |
format | Online Article Text |
id | pubmed-8495839 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-84958392021-10-08 Sepiolite Nanocarriers as a Matrix for Controlled Thermal Energy Storage Zhu, Xiaolei Vinokurov, Vladimir Kopitsyn, Dmitry Shchukin, Dmitry G. ACS Omega [Image: see text] Applying the eutectic hydrated salt (EHS) mixture of Na(2)HPO(4)·12H(2)O and Na(2)SO(4)·10H(2)O in a 1:1 weight ratio as a phase-change material and natural sepiolite nanocarriers as a matrix, the form-stable phase-change composite EHS@sepiolite was fabricated by vacuum impregnation. Due to the high porosity of sepiolite and its nanofibrous structure with internal channels, the effective loading of the phase-change material reached as high as 88 wt %. The melting temperature of the composite was 38.1 °C and its melting enthalpy was 185 J g(–1.) The crystallinity of the hydrated salt mixture was retained after loading into the sepiolite matrix. The composite demonstrated high stability over 50 heat uptake/release cycles maintaining its melting temperature and melting enthalpy the same. The combination of natural sepiolite nanocarriers and crystallohydrates is a cheap and efficient nanoscale energy storage system with high potential for practical applications and upscaling because of their natural abundance. American Chemical Society 2021-09-20 /pmc/articles/PMC8495839/ /pubmed/34632238 http://dx.doi.org/10.1021/acsomega.1c04392 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Zhu, Xiaolei Vinokurov, Vladimir Kopitsyn, Dmitry Shchukin, Dmitry G. Sepiolite Nanocarriers as a Matrix for Controlled Thermal Energy Storage |
title | Sepiolite Nanocarriers as a Matrix for Controlled
Thermal Energy Storage |
title_full | Sepiolite Nanocarriers as a Matrix for Controlled
Thermal Energy Storage |
title_fullStr | Sepiolite Nanocarriers as a Matrix for Controlled
Thermal Energy Storage |
title_full_unstemmed | Sepiolite Nanocarriers as a Matrix for Controlled
Thermal Energy Storage |
title_short | Sepiolite Nanocarriers as a Matrix for Controlled
Thermal Energy Storage |
title_sort | sepiolite nanocarriers as a matrix for controlled
thermal energy storage |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8495839/ https://www.ncbi.nlm.nih.gov/pubmed/34632238 http://dx.doi.org/10.1021/acsomega.1c04392 |
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