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Low-oxidation state cobalt–magnesium complexes: ion-pairing and reactivity

Magnesium cobaltates ((Ar)nacnac)MgCo(COD)(2) (1–3) were synthesised by reacting ((Ar)nacnac)MgI(OEt(2)) with K[Co(η(4)-COD)(2)] (COD = 1,5-cyclooctadiene) [(Ar)nacnac = CH(ArNCMe)(2); Ar = 2,4,6-Me(3)-C(6)H(2) (Mes), 2,6-Et(2)-C(6)H(3) (Dep), 2,6-iPr(2)-C(6)H(3)Mes (Dipp)]. Compounds 1–3 form conta...

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Detalles Bibliográficos
Autores principales:	Kelly, John A., Gramüller, Johannes, Gschwind, Ruth M., Wolf, Robert
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8507399/ https://www.ncbi.nlm.nih.gov/pubmed/34542141 http://dx.doi.org/10.1039/d1dt02621f

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