Cargando…

Bidentate Lewis Acids Derived from o‐Diethynylbenzene with Group 13 and 14 Functions

Starting from 1,2‐diethynylbenzene, a series of bidentate Lewis acids was prepared by means of hydrometalations, in particular hydrosilylation, hydroboration, hydroalumination and terminal metalation based on group 13 and 14 elements. In the case of terminal alkyne metalation, the Lewis‐acidic galli...

Descripción completa

Detalles Bibliográficos
Autores principales:	Rudlof, Jens, Aders, Niklas, Lamm, Jan‐Hendrik, Neumann, Beate, Stammler, Hans‐Georg, Mitzel, Norbert W.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8507440/ https://www.ncbi.nlm.nih.gov/pubmed/34637192 http://dx.doi.org/10.1002/open.202100198

Ejemplares similares

Carbon dioxide reduction by an Al–O–P frustrated Lewis pair
por: Wickemeyer, Lucas, et al.
Publicado: (2022)

Exploring the Reactivity of a Frustrated Sn/P Lewis Pair: The Highly Selective Complexation of the cis‐Azobenzene Photoisomer
por: Holtkamp, Philipp, et al.
Publicado: (2021)

A Rational Approach to Tetra‐Functional Photo‐Switches
por: Niermeier, Philipp, et al.
Publicado: (2019)

Chalice‐Type Tridentate Silicon Lewis Acids of C (3) Symmetry in a Single Step Starting from Hexadehydrotribenzo[12]annulene
por: Schwartzen, Anna, et al.
Publicado: (2020)

Hydrogen-bond-induced selectivity of a head-to-head photo-dimerisation of dialkynylanthracene – access to tetradentate Lewis acids
por: Niermeier, Philipp, et al.
Publicado: (2021)

Differences in the Reactivity of Geminal Si−O−P and Al−O−P Frustrated Lewis Pairs
por: Wickemeyer, Lucas, et al.
Publicado: (2022)

An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair
por: Holtkamp, Philipp, et al.
Publicado: (2020)

Inter‐ and Intramolecular Aryl–Aryl Interactions in Partially Fluorinated Ethylenedioxy‐bridged Bisarenes
por: Weddeling, Jan‐Henrik, et al.
Publicado: (2020)

Co‐Crystal Formation of Partially Fluorinated 1,3,5‐Tris(phenylethynyl)benzenes
por: Weddeling, Jan‐Henrik, et al.
Publicado: (2021)

Poly-pnictogen bonding: trapping halide ions by a tetradentate antimony(iii) Lewis acid
por: Beckmann, J. Louis, et al.
Publicado: (2023)

Regiochemical Control in Triptycene Formation—An Exercise in Subtle Balancing Multiple Factors
por: Lamm, Jan‐Hendrik, et al.
Publicado: (2018)

An air-stable bisboron complex: a practical bidentate Lewis acid catalyst
por: Hong, Longcheng, et al.
Publicado: (2018)

Isolation of a 16π‐Electrons 1,4‐Diphosphinine‐1,4‐diide with a Planar C(4)P(2) Ring
por: Rottschäfer, Dennis, et al.
Publicado: (2021)

A Zwitterionic Phosphonium Stannate(II) via Hydrogen Splitting by a Sn/P Frustrated Lewis‐Pair and Reductive Elimination
por: Holtkamp, Philipp, et al.
Publicado: (2020)

Asymmetric synthesis of propargylamines as amino acid surrogates in peptidomimetics
por: Wünsch, Matthias, et al.
Publicado: (2017)

Non‐coordinated and Hydrogen Bonded Phenolate Anions as One‐Electron Reducing Agents
por: Weitkamp, Robin F., et al.
Publicado: (2021)

2-Phenyl-tetrahydropyrimidine-4(1H)-ones – cyclic benzaldehyde aminals as precursors for functionalised β(2)-amino acids
por: Nahrwold, Markus, et al.
Publicado: (2009)

Evidence of the Lewis‐Amphoteric Character of Tris(pentafluoroethyl)silanide, [Si(C(2)F(5))(3)](−)
por: Tiessen, Natalia, et al.
Publicado: (2021)

Preparation of an ion with the highest calculated proton affinity: ortho-diethynylbenzene dianion
por: Poad, Berwyck L. J., et al.
Publicado: (2016)

Anionic Polymerization of Para-Diethynylbenzene: Synthesis of a Strictly Linear Polymer
por: Misin, Vyacheslav M., et al.
Publicado: (2022)

Isolation of 1,4‐Diarsinine‐1,4‐diide and 1,4‐Diarsinine Derivatives
por: Rottschäfer, Dennis, et al.
Publicado: (2021)

Spectroscopic Properties, Conformation and Structure of Difluorothiophosphoryl Isocyanate in the Gaseous and Solid Phase
por: Schwabedissen, Jan, et al.
Publicado: (2020)

Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants
por: Schwabedissen, Jan, et al.
Publicado: (2020)

Tris(pentafluoroethyl)silanol Derivatives and the Lewis Amphoteric Tris(pentafluoroethyl)silanolate Anion, [Si(C(2)F(5))(3)O](−)
por: Tiessen, Natalia, et al.
Publicado: (2021)

The Nature of Chalcogen‐Bonding‐Type Tellurium–Nitrogen Interactions: A First Experimental Structure from the Gas Phase
por: Glodde, Timo, et al.
Publicado: (2020)

Aryl–Aryl Interactions in (Aryl‐Perhalogenated) 1,2‐Diaryldisilanes
por: Linnemannstöns, Marvin, et al.
Publicado: (2020)

Synthesis and Coordination Behavior of a New Hybrid Bidentate Ligand with Phosphine and Silylene Donors
por: Nazish, Mohd, et al.
Publicado: (2020)

Catalysis by Bidentate Iodine(III)-Based Halogen Donors: Surpassing the Activity of Strong Lewis Acids
por: Portela, Susana, et al.
Publicado: (2021)

Synthesis and Characterization of Block Copolymers of Poly(silylene diethynylbenzen) and Poly(silylene dipropargyl aryl ether)
por: Gao, Man, et al.
Publicado: (2021)

A Highly Active Bidentate Magnesium Catalyst for Amine‐Borane Dehydrocoupling: Kinetic and Mechanistic Studies
por: Ried, Alexander C. A., et al.
Publicado: (2019)

Mesoionic Dithiolates (MIDts) Derived from 1,3‐Imidazole‐Based Anionic Dicarbenes (ADCs)
por: Ebeler, Falk, et al.
Publicado: (2022)

Selective Preparation of a Heteroleptic Cyclometallated Ruthenium Complex Capable of Undergoing Photosubstitution of a Bidentate Ligand
por: Cuello‐Garibo, Jordi‐Amat, et al.
Publicado: (2018)

Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands
por: Sharma, Mahendra K., et al.
Publicado: (2021)

Enhancing Performance and Stability of Perovskite Solar Cells through Surface Defect Passivation with Organic Bidentate Lewis Bases
por: Yan, Weibo, et al.
Publicado: (2022)

A New Polymer-Based Fluorescent Chemosensor Incorporating Propane-1,3-Dione and 2,5-Diethynylbenzene Moieties for Detection of Copper(II) and Iron(III)
por: Yang, Dongliang, et al.
Publicado: (2017)

Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)borylbenzenes and o-(Difluorosilyl)borylbenzenes, and Their Fluoride Ion Affinities
por: Shimada, Junpei, et al.
Publicado: (2022)

Latent ruthenium–indenylidene catalysts bearing a N-heterocyclic carbene and a bidentate picolinate ligand
por: Schmid, Thibault E, et al.
Publicado: (2015)

Crystal Structures of the Carborane Dianions [1,4-(PhCB(10)H(10)C)(2)C(6)H(4)](2−) and [1,4-(PhCB(10)H(10)C)(2)C(6)F(4)](2−) and the Stabilizing Role of the para-Phenylene Unit on 2 n+3 Skeletal Electron Clusters**
por: Kahlert, Jan, et al.
Publicado: (2014)

Effects of the Bidentate Ligand on the Photophysical Properties, Cellular Uptake, and (Photo)cytotoxicity of Glycoconjugates Based on the [Ru(tpy)(NN)(L)](2+) Scaffold
por: Lameijer, Lucien N., et al.
Publicado: (2018)

Non‐Oxido‐Vanadium(IV) Metalloradical Complexes with Bidentate 1,2‐Dithienylethene Ligands: Observation of Reversible Cyclization of the Ligand Scaffold in Solution
por: Schlüter, Dirk, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_vqisv6kueqm6knr8p9j8utmms1