Cargando…

Ionic Liquid-Assisted Grinding: An Electrophilic Fluorination Benchmark

We demonstrated the influence of liquid additives on the rate and selectivity of mechanochemical fluorination of aromatic and 1,3-dicarbonyl compounds with F-TEDA-BF(4). Substoichiometric catalytic quantities of ionic liquids speed up the reaction. We proposed an improved protocol for ionic liquids-...

Descripción completa

Detalles Bibliográficos
Autores principales:	Zaikin, Pavel A., Dyan, Ok Ton, Elanov, Innokenty R., Borodkin, Gennady I.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8510021/ https://www.ncbi.nlm.nih.gov/pubmed/34641300 http://dx.doi.org/10.3390/molecules26195756

Ejemplares similares

Triphilic Ionic-Liquid Mixtures: Fluorinated and Non-fluorinated Aprotic Ionic-Liquid Mixtures
por: Hollóczki, Oldamur, et al.
Publicado: (2015)

Bismuthene nanosheets produced by ionic liquid assisted grinding exfoliation and their use for oxygen reduction reaction
por: Ozhukil Valappil, Manila, et al.
Publicado: (2020)

Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine
por: Han, Jianlin, et al.
Publicado: (2020)

Highly‐fluorinated Triaminocyclopropenium Ionic Liquids
por: Curnow, Owen J., et al.
Publicado: (2022)

Kinetics of Electrophilic Fluorination of Steroids and Epimerisation of Fluorosteroids
por: Rozatian, Neshat, et al.
Publicado: (2020)

Correction: Bismuthene nanosheets produced by ionic liquid assisted grinding exfoliation and their use for oxygen reduction reaction
por: Valappil, Manila Ozhukil, et al.
Publicado: (2021)

A quantitative reactivity scale for electrophilic fluorinating reagents
por: Rozatian, Neshat, et al.
Publicado: (2018)

Fluorocarbyne complexes via electrophilic fluorination of carbido ligands
por: Manzano, Richard A., et al.
Publicado: (2023)

Tailor-Made Fluorinated Ionic Liquids for Protein Delivery
por: Vieira, N. S. M., et al.
Publicado: (2020)

Fluorine-functionalized ionic liquids with high oxygen solubility
por: Vanhoutte, Gijs, et al.
Publicado: (2018)

Ionic Liquids as Organocatalysts for Nucleophilic Fluorination: Concepts and Perspectives
por: Oh, Young-Ho, et al.
Publicado: (2022)

Effect of Aromaticity in Anion on the Cation–Anion Interactions and Ionic Mobility in Fluorine-Free Ionic Liquids
por: Khan, Inayat Ali, et al.
Publicado: (2020)

Temperature‐Dependent Surface Enrichment Effects in Binary Mixtures of Fluorinated and Non‐Fluorinated Ionic Liquids
por: Heller, Bettina S. J., et al.
Publicado: (2020)

Studies on the Interaction between Model Proteins and Fluorinated Ionic Liquids
por: Alves, Márcia M. S., et al.
Publicado: (2023)

Dramatic Influence of Ionic Liquid and Ultrasound Irradiation on the Electrophilic Sulfinylation of Aromatic Compounds by Sulfinic Esters
por: Nguyen, Ngoc-Lan Thi, et al.
Publicado: (2017)

Synthesis of Fluorinated 3,6-Dihydropyridines and 2-(Fluoromethyl)pyridines by Electrophilic Fluorination of 1,2-Dihydropyridines with Selectfluor(®)
por: Pikun, Nadiia V., et al.
Publicado: (2020)

Fluorine-free, liquid-repellent surfaces made from ionic liquid-infused nanostructured silicon
por: Bittner, Roland W., et al.
Publicado: (2016)

Structural and Ion Dynamics in Fluorine-Free Oligoether Carboxylate Ionic Liquid-Based Electrolytes
por: Shah, Faiz Ullah, et al.
Publicado: (2020)

Innovative Syntheses of Cyano(fluoro)borates: Catalytic Cyanation, Electrochemical and Electrophilic Fluorination
por: Drisch, Michael, et al.
Publicado: (2020)

Flexibility is the key to tuning the transport properties of fluorinated imide-based ionic liquids
por: Philippi, Frederik, et al.
Publicado: (2022)

Design of Ionic Liquids for Fluorinated Gas Absorption: COSMO-RS Selection and Solubility Experiments
por: Sosa, Julio E., et al.
Publicado: (2022)

Disclosing the Potential of Fluorinated Ionic Liquids as Interferon-Alpha 2b Delivery Systems
por: Ferreira, Margarida L., et al.
Publicado: (2022)

How Cinchona Alkaloid-Derived Primary Amines Control Asymmetric Electrophilic Fluorination of Cyclic Ketones
por: Lam, Yu-hong, et al.
Publicado: (2014)

Electrophilic Fluorination of Alkenes via Bora‐Wagner–Meerwein Rearrangement. Access to β‐Difluoroalkyl Boronates
por: Wang, Qiang, et al.
Publicado: (2021)

Impact of Fluorinated Ionic Liquids on Human Phenylalanine Hydroxylase—A Potential Drug Delivery System
por: Alves, Márcia M. S., et al.
Publicado: (2022)

Catalytic Nucleophilic Fluorination of Secondary and Tertiary Propargylic Electrophiles with a Copper–N-Heterocyclic Carbene Complex
por: Cheng, Li-Jie, et al.
Publicado: (2015)

The Synthesis of Poly(Vinyl Alcohol) Grafted with Fluorinated Protic Ionic Liquids Containing Sulfo Functional Groups
por: Glińska, Patrycja, et al.
Publicado: (2021)

Ionogels Derived from Fluorinated Ionic Liquids to Enhance Aqueous Drug Solubility for Local Drug Administration
por: Hermida-Merino, Carolina, et al.
Publicado: (2022)

Poly Caprolactam Supported Hexaethylene Glycolic Imidazolium Ionic Liquid as a Heterogeneous Promoter for Nucleophilic Fluorination
por: Reddy, Mudumala Veeranarayana, et al.
Publicado: (2023)

Ionic Liquid assisted Synthesis of Zeolite-TON
por: Tian, Yuyang, et al.
Publicado: (2014)

Properties of Dicationic Disiloxane Ionic Liquids
por: Krasovskiy, Vladimir G., et al.
Publicado: (2020)

Solid Contact Potentiometric Sensors Based on a New Class of Ionic Liquids on Thiacalixarene Platform
por: Padnya, Pavel L., et al.
Publicado: (2018)

Liquid-assisted grinding and ion pairing regulates percentage conversion and diastereoselectivity of the Wittig reaction under mechanochemical conditions
por: Denlinger, Kendra Leahy, et al.
Publicado: (2018)

Controlling the stereochemistry in 2-oxo-aldehyde-derived Ugi adducts through the cinchona alkaloid-promoted electrophilic fluorination
por: Wang, Yuqing, et al.
Publicado: (2020)

Harnessing Ionic Interactions and Hydrogen Bonding for Nucleophilic Fluorination
por: Oh, Young-Ho, et al.
Publicado: (2020)

Origin of Salt Effects in S(N)2 Fluorination Using KF Promoted by Ionic Liquids: Quantum Chemical Analysis
por: Oh, Young-Ho, et al.
Publicado: (2021)

Life Cycle Assessment of the Separation and Recycling of Fluorinated Gases Using Ionic Liquids in a Circular Economy Framework
por: Jovell, Daniel, et al.
Publicado: (2021)

Effect of Different Solvents on Morphology and Gas-Sensitive Properties of Grinding-Assisted Liquid-Phase-Exfoliated MoS(2) Nanosheets
por: Wang, Hao, et al.
Publicado: (2022)

Investigating the Effect of Grinding Time on High-Speed Grinding of Rails by a Passive Grinding Test Machine
por: Liu, Pengzhan, et al.
Publicado: (2022)

Electrophile Signaling and Emerging Immuno- and Neuro-modulatory Electrophilic Pharmaceuticals
por: Poganik, Jesse R., et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_lkvshtn2ceau6ojt3iq50pdoj7