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Origin of Salt Effects in S(N)2 Fluorination Using KF Promoted by Ionic Liquids: Quantum Chemical Analysis
Quantum chemical analysis is presented, motivated by Grée and co-workers’ observation of salt effects [Adv. Synth. Catal. 2006, 348, 1149–1153] for S(N)2 fluorination of KF in ionic liquids (ILs). We examine the relative promoting capacity of KF in [bmim]PF(6) vs. [bmim]Cl by comparing the activatio...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8510065/ https://www.ncbi.nlm.nih.gov/pubmed/34641282 http://dx.doi.org/10.3390/molecules26195738 |