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Sorption and Micro-Scale Strength Properties of Coals Susceptible to Outburst Caused by Changes in Degree of Coalification

Coals from the south-western part of the Upper Silesian Coal Basin have a strong outburst susceptibility. The objective of this study was to identify the influence of coalification degree on methane sorption and micro scale strength properties of 24 coals from Jastrzębie Zdrój. Coal samples showed a...

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Autores principales: Godyń, Katarzyna, Dutka, Barbara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8510263/
https://www.ncbi.nlm.nih.gov/pubmed/34640204
http://dx.doi.org/10.3390/ma14195807
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author Godyń, Katarzyna
Dutka, Barbara
author_facet Godyń, Katarzyna
Dutka, Barbara
author_sort Godyń, Katarzyna
collection PubMed
description Coals from the south-western part of the Upper Silesian Coal Basin have a strong outburst susceptibility. The objective of this study was to identify the influence of coalification degree on methane sorption and micro scale strength properties of 24 coals from Jastrzębie Zdrój. Coal samples showed a reflectance R(o) between 0.98 and 1.25%. Sorption measurements were carried out by gravimetric method. Sorption capacities were determined at mean deposit temperature of 35 °C. Using the unipore model and solution of Fick’s second law, the effective diffusion coefficients of methane in the studied coals were obtained. The Vickers method was used to study the microhardness and the modulus of elasticity. It has been shown that the increase in the coalification degree reduces the sorption capacity of coal and also reduces the rate of methane emission. Coals the most susceptible to outbursts, were the most brittle. With the increase in R(o), the methane seam pressure p increased as well as desorbable methane content DMC, both due to the reduction in the sorption capacity of coal. The increased dp index is a warning sign indicating an increased total methane content of coal seam, an increased seam pressure or an alternation of coal structure.
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spelling pubmed-85102632021-10-13 Sorption and Micro-Scale Strength Properties of Coals Susceptible to Outburst Caused by Changes in Degree of Coalification Godyń, Katarzyna Dutka, Barbara Materials (Basel) Article Coals from the south-western part of the Upper Silesian Coal Basin have a strong outburst susceptibility. The objective of this study was to identify the influence of coalification degree on methane sorption and micro scale strength properties of 24 coals from Jastrzębie Zdrój. Coal samples showed a reflectance R(o) between 0.98 and 1.25%. Sorption measurements were carried out by gravimetric method. Sorption capacities were determined at mean deposit temperature of 35 °C. Using the unipore model and solution of Fick’s second law, the effective diffusion coefficients of methane in the studied coals were obtained. The Vickers method was used to study the microhardness and the modulus of elasticity. It has been shown that the increase in the coalification degree reduces the sorption capacity of coal and also reduces the rate of methane emission. Coals the most susceptible to outbursts, were the most brittle. With the increase in R(o), the methane seam pressure p increased as well as desorbable methane content DMC, both due to the reduction in the sorption capacity of coal. The increased dp index is a warning sign indicating an increased total methane content of coal seam, an increased seam pressure or an alternation of coal structure. MDPI 2021-10-04 /pmc/articles/PMC8510263/ /pubmed/34640204 http://dx.doi.org/10.3390/ma14195807 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Godyń, Katarzyna
Dutka, Barbara
Sorption and Micro-Scale Strength Properties of Coals Susceptible to Outburst Caused by Changes in Degree of Coalification
title Sorption and Micro-Scale Strength Properties of Coals Susceptible to Outburst Caused by Changes in Degree of Coalification
title_full Sorption and Micro-Scale Strength Properties of Coals Susceptible to Outburst Caused by Changes in Degree of Coalification
title_fullStr Sorption and Micro-Scale Strength Properties of Coals Susceptible to Outburst Caused by Changes in Degree of Coalification
title_full_unstemmed Sorption and Micro-Scale Strength Properties of Coals Susceptible to Outburst Caused by Changes in Degree of Coalification
title_short Sorption and Micro-Scale Strength Properties of Coals Susceptible to Outburst Caused by Changes in Degree of Coalification
title_sort sorption and micro-scale strength properties of coals susceptible to outburst caused by changes in degree of coalification
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8510263/
https://www.ncbi.nlm.nih.gov/pubmed/34640204
http://dx.doi.org/10.3390/ma14195807
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