Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients

We propose and test an efficient approach for the assessment of the enthalpies of vaporization of ionic liquids at the reference temperature 298.15 K. The approach is based on activity coefficients at infinite dilution of volatile organic solutes in ionic liquids bearing the imidazolium cation of th...

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Detalles Bibliográficos
Autor principal: Verevkin, Sergey P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8510351/
https://www.ncbi.nlm.nih.gov/pubmed/34641417
http://dx.doi.org/10.3390/molecules26195873
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author Verevkin, Sergey P.
author_facet Verevkin, Sergey P.
author_sort Verevkin, Sergey P.
collection PubMed
description We propose and test an efficient approach for the assessment of the enthalpies of vaporization of ionic liquids at the reference temperature 298.15 K. The approach is based on activity coefficients at infinite dilution of volatile organic solutes in ionic liquids bearing the imidazolium cation of the general formula [C(n)mim][Anion].
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spelling pubmed-85103512021-10-13 Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients Verevkin, Sergey P. Molecules Review We propose and test an efficient approach for the assessment of the enthalpies of vaporization of ionic liquids at the reference temperature 298.15 K. The approach is based on activity coefficients at infinite dilution of volatile organic solutes in ionic liquids bearing the imidazolium cation of the general formula [C(n)mim][Anion]. MDPI 2021-09-28 /pmc/articles/PMC8510351/ /pubmed/34641417 http://dx.doi.org/10.3390/molecules26195873 Text en © 2021 by the author. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Verevkin, Sergey P.
Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients
title Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients
title_full Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients
title_fullStr Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients
title_full_unstemmed Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients
title_short Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients
title_sort imidazolium based ionic liquids: unbiased recovering of vaporization enthalpies from infinite-dilution activity coefficients
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8510351/
https://www.ncbi.nlm.nih.gov/pubmed/34641417
http://dx.doi.org/10.3390/molecules26195873
work_keys_str_mv AT verevkinsergeyp imidazoliumbasedionicliquidsunbiasedrecoveringofvaporizationenthalpiesfrominfinitedilutionactivitycoefficients

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