Cargando…

The Amine Functionalized Sugarcane Bagasse Biocomposites as Magnetically Adsorbent for Contaminants Removal in Aqueous Solution

The method of solvothermal by one-step operation has been performed to synthesize of magnetic amine-functionalized sugarcane bagasse biocomposites (SB-MH). The obtained SB-MH contains 62.34% of Fe, 17.8 mmol/g of amine, and a magnetic property of 19.46 emu/g. The biocomposite surface area increased...

Descripción completa

Detalles Bibliográficos
Autores principales: Irawan, Chairul, Putra, Meilana Dharma, Wijayanti, Hesti, Juwita, Rinna, Meliana, Yenny, Nata, Iryanti Fatyasari
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8510407/
https://www.ncbi.nlm.nih.gov/pubmed/34641411
http://dx.doi.org/10.3390/molecules26195867
_version_ 1784582564486316032
author Irawan, Chairul
Putra, Meilana Dharma
Wijayanti, Hesti
Juwita, Rinna
Meliana, Yenny
Nata, Iryanti Fatyasari
author_facet Irawan, Chairul
Putra, Meilana Dharma
Wijayanti, Hesti
Juwita, Rinna
Meliana, Yenny
Nata, Iryanti Fatyasari
author_sort Irawan, Chairul
collection PubMed
description The method of solvothermal by one-step operation has been performed to synthesize of magnetic amine-functionalized sugarcane bagasse biocomposites (SB-MH). The obtained SB-MH contains 62.34% of Fe, 17.8 mmol/g of amine, and a magnetic property of 19.46 emu/g. The biocomposite surface area increased significantly from 1.617 to 25.789 m(2)/g after amine functionalization. The optimum condition of SB-MH used for Pb(II) ion removal was achieved at pH 5 for 360 min with adsorption capacity of 203.522 mg/g. The pseudo 2nd order was well-fitted to the model of Pb(II) ion adsorption. Meanwhile, other contaminant parameters number of Chemical Oxygen Demand (COD), Total Suspended Solid (TSS), and dye in wastewater were also remarkably reduced by about 74.4%, 88.0%, and 96.7%, respectively. The reusability of SB-MH with 4th repetitions showed only a slight decrease in performance of 5%. Therefore, the proposed magnetic amine-functionalized sugarcane bagasse biocomposites lead to a very potential adsorbent implemented in high scale due to high surface area, easy separation, stable materials and capability to adsorb contaminants from aqueous solution.
format Online
Article
Text
id pubmed-8510407
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-85104072021-10-13 The Amine Functionalized Sugarcane Bagasse Biocomposites as Magnetically Adsorbent for Contaminants Removal in Aqueous Solution Irawan, Chairul Putra, Meilana Dharma Wijayanti, Hesti Juwita, Rinna Meliana, Yenny Nata, Iryanti Fatyasari Molecules Article The method of solvothermal by one-step operation has been performed to synthesize of magnetic amine-functionalized sugarcane bagasse biocomposites (SB-MH). The obtained SB-MH contains 62.34% of Fe, 17.8 mmol/g of amine, and a magnetic property of 19.46 emu/g. The biocomposite surface area increased significantly from 1.617 to 25.789 m(2)/g after amine functionalization. The optimum condition of SB-MH used for Pb(II) ion removal was achieved at pH 5 for 360 min with adsorption capacity of 203.522 mg/g. The pseudo 2nd order was well-fitted to the model of Pb(II) ion adsorption. Meanwhile, other contaminant parameters number of Chemical Oxygen Demand (COD), Total Suspended Solid (TSS), and dye in wastewater were also remarkably reduced by about 74.4%, 88.0%, and 96.7%, respectively. The reusability of SB-MH with 4th repetitions showed only a slight decrease in performance of 5%. Therefore, the proposed magnetic amine-functionalized sugarcane bagasse biocomposites lead to a very potential adsorbent implemented in high scale due to high surface area, easy separation, stable materials and capability to adsorb contaminants from aqueous solution. MDPI 2021-09-28 /pmc/articles/PMC8510407/ /pubmed/34641411 http://dx.doi.org/10.3390/molecules26195867 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Irawan, Chairul
Putra, Meilana Dharma
Wijayanti, Hesti
Juwita, Rinna
Meliana, Yenny
Nata, Iryanti Fatyasari
The Amine Functionalized Sugarcane Bagasse Biocomposites as Magnetically Adsorbent for Contaminants Removal in Aqueous Solution
title The Amine Functionalized Sugarcane Bagasse Biocomposites as Magnetically Adsorbent for Contaminants Removal in Aqueous Solution
title_full The Amine Functionalized Sugarcane Bagasse Biocomposites as Magnetically Adsorbent for Contaminants Removal in Aqueous Solution
title_fullStr The Amine Functionalized Sugarcane Bagasse Biocomposites as Magnetically Adsorbent for Contaminants Removal in Aqueous Solution
title_full_unstemmed The Amine Functionalized Sugarcane Bagasse Biocomposites as Magnetically Adsorbent for Contaminants Removal in Aqueous Solution
title_short The Amine Functionalized Sugarcane Bagasse Biocomposites as Magnetically Adsorbent for Contaminants Removal in Aqueous Solution
title_sort amine functionalized sugarcane bagasse biocomposites as magnetically adsorbent for contaminants removal in aqueous solution
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8510407/
https://www.ncbi.nlm.nih.gov/pubmed/34641411
http://dx.doi.org/10.3390/molecules26195867
work_keys_str_mv AT irawanchairul theaminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT putrameilanadharma theaminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT wijayantihesti theaminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT juwitarinna theaminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT melianayenny theaminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT natairyantifatyasari theaminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT irawanchairul aminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT putrameilanadharma aminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT wijayantihesti aminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT juwitarinna aminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT melianayenny aminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution
AT natairyantifatyasari aminefunctionalizedsugarcanebagassebiocompositesasmagneticallyadsorbentforcontaminantsremovalinaqueoussolution