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Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle
Poly(ethylene 2,5-furandicarboxylate), PEF and poly(ethylene terephthalate), PET, are two polyesters with close chemical structures. It leads to similar thermal, mechanical and barrier properties. In order to optimize their stretching, a strategy based on the time/temperature principle is used. The...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8512310/ https://www.ncbi.nlm.nih.gov/pubmed/34641111 http://dx.doi.org/10.3390/polym13193295 |
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author | Forestier, Emilie Combeaud, Christelle Guigo, Nathanael Corvec, Guillaume Pradille, Christophe Sbirrazzuoli, Nicolas Billon, Noelle |
author_facet | Forestier, Emilie Combeaud, Christelle Guigo, Nathanael Corvec, Guillaume Pradille, Christophe Sbirrazzuoli, Nicolas Billon, Noelle |
author_sort | Forestier, Emilie |
collection | PubMed |
description | Poly(ethylene 2,5-furandicarboxylate), PEF and poly(ethylene terephthalate), PET, are two polyesters with close chemical structures. It leads to similar thermal, mechanical and barrier properties. In order to optimize their stretching, a strategy based on the time/temperature principle is used. The building of master curves, in the linear visco-elastic domain, allows the identification of the experimental conditions for which the two materials are in the same physical state. The initial physical state of the materials is important as, to fit with the industrial constrains, the polymers must reach high level of deformation, and develop strain induced crystallization (SIC). In this paper, the screening of the forming range is described, as well as the mechanical response depending on the stretching settings. Moreover, the same mechanical response can exist for PEF and PET if the same gap from the α-relaxation exists. |
format | Online Article Text |
id | pubmed-8512310 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-85123102021-10-14 Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle Forestier, Emilie Combeaud, Christelle Guigo, Nathanael Corvec, Guillaume Pradille, Christophe Sbirrazzuoli, Nicolas Billon, Noelle Polymers (Basel) Article Poly(ethylene 2,5-furandicarboxylate), PEF and poly(ethylene terephthalate), PET, are two polyesters with close chemical structures. It leads to similar thermal, mechanical and barrier properties. In order to optimize their stretching, a strategy based on the time/temperature principle is used. The building of master curves, in the linear visco-elastic domain, allows the identification of the experimental conditions for which the two materials are in the same physical state. The initial physical state of the materials is important as, to fit with the industrial constrains, the polymers must reach high level of deformation, and develop strain induced crystallization (SIC). In this paper, the screening of the forming range is described, as well as the mechanical response depending on the stretching settings. Moreover, the same mechanical response can exist for PEF and PET if the same gap from the α-relaxation exists. MDPI 2021-09-27 /pmc/articles/PMC8512310/ /pubmed/34641111 http://dx.doi.org/10.3390/polym13193295 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Forestier, Emilie Combeaud, Christelle Guigo, Nathanael Corvec, Guillaume Pradille, Christophe Sbirrazzuoli, Nicolas Billon, Noelle Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle |
title | Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle |
title_full | Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle |
title_fullStr | Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle |
title_full_unstemmed | Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle |
title_short | Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle |
title_sort | comparative analysis of the mechanical behaviour of pef and pet uniaxial stretching based on the time/temperature superposition principle |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8512310/ https://www.ncbi.nlm.nih.gov/pubmed/34641111 http://dx.doi.org/10.3390/polym13193295 |
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