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Azine-N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation

Heterocycle-derived aldehydes are challenging substrates in metal-catalysed hydroacylation chemistry. We show that by using azine N-oxide substituted aldehydes, good reactivity can be achieved, and that they are highly effective substrates for the intermolecular hydroacylation of alkynes. Employing...

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Detalles Bibliográficos
Autores principales: Moseley, Daniel F., Kalepu, Jagadeesh, Willis, Michael C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8513814/
https://www.ncbi.nlm.nih.gov/pubmed/34745537
http://dx.doi.org/10.1039/d1sc03915f