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Transition metal-catalyzed organic reactions in undivided electrochemical cells
Transition metal-catalyzed organic electrochemistry is a rapidly growing research area owing in part to the ability of metal catalysts to alter the selectivity of a given transformation. This conversion mainly focuses on transition metal-catalyzed anodic oxidation and cathodic reduction and great pr...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8514006/ https://www.ncbi.nlm.nih.gov/pubmed/34745519 http://dx.doi.org/10.1039/d1sc04011a |
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author | Ma, Cong Fang, Ping Liu, Dong Jiao, Ke-Jin Gao, Pei-Sen Qiu, Hui Mei, Tian-Sheng |
author_facet | Ma, Cong Fang, Ping Liu, Dong Jiao, Ke-Jin Gao, Pei-Sen Qiu, Hui Mei, Tian-Sheng |
author_sort | Ma, Cong |
collection | PubMed |
description | Transition metal-catalyzed organic electrochemistry is a rapidly growing research area owing in part to the ability of metal catalysts to alter the selectivity of a given transformation. This conversion mainly focuses on transition metal-catalyzed anodic oxidation and cathodic reduction and great progress has been achieved in both areas. Typically, only one of the half-cell reactions is involved in the organic reaction while a sacrificial reaction occurs at the counter electrode, which is inherently wasteful since one electrode is not being used productively. Recently, transition metal-catalyzed paired electrolysis that makes use of both anodic oxidation and cathodic reduction has attracted much attention. This perspective highlights the recent progress of each type of electrochemical reaction and relatively focuses on the transition metal-catalyzed paired electrolysis, showcasing that electrochemical reactions involving transition metal catalysis have advantages over conventional reactions in terms of controlling the reaction activity and selectivity and figuring out that transition metal-catalyzed paired electrolysis is an important direction of organic electrochemistry in the future and offers numerous opportunities for new and improved organic reaction methods. |
format | Online Article Text |
id | pubmed-8514006 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-85140062021-11-04 Transition metal-catalyzed organic reactions in undivided electrochemical cells Ma, Cong Fang, Ping Liu, Dong Jiao, Ke-Jin Gao, Pei-Sen Qiu, Hui Mei, Tian-Sheng Chem Sci Chemistry Transition metal-catalyzed organic electrochemistry is a rapidly growing research area owing in part to the ability of metal catalysts to alter the selectivity of a given transformation. This conversion mainly focuses on transition metal-catalyzed anodic oxidation and cathodic reduction and great progress has been achieved in both areas. Typically, only one of the half-cell reactions is involved in the organic reaction while a sacrificial reaction occurs at the counter electrode, which is inherently wasteful since one electrode is not being used productively. Recently, transition metal-catalyzed paired electrolysis that makes use of both anodic oxidation and cathodic reduction has attracted much attention. This perspective highlights the recent progress of each type of electrochemical reaction and relatively focuses on the transition metal-catalyzed paired electrolysis, showcasing that electrochemical reactions involving transition metal catalysis have advantages over conventional reactions in terms of controlling the reaction activity and selectivity and figuring out that transition metal-catalyzed paired electrolysis is an important direction of organic electrochemistry in the future and offers numerous opportunities for new and improved organic reaction methods. The Royal Society of Chemistry 2021-08-24 /pmc/articles/PMC8514006/ /pubmed/34745519 http://dx.doi.org/10.1039/d1sc04011a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Ma, Cong Fang, Ping Liu, Dong Jiao, Ke-Jin Gao, Pei-Sen Qiu, Hui Mei, Tian-Sheng Transition metal-catalyzed organic reactions in undivided electrochemical cells |
title | Transition metal-catalyzed organic reactions in undivided electrochemical cells |
title_full | Transition metal-catalyzed organic reactions in undivided electrochemical cells |
title_fullStr | Transition metal-catalyzed organic reactions in undivided electrochemical cells |
title_full_unstemmed | Transition metal-catalyzed organic reactions in undivided electrochemical cells |
title_short | Transition metal-catalyzed organic reactions in undivided electrochemical cells |
title_sort | transition metal-catalyzed organic reactions in undivided electrochemical cells |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8514006/ https://www.ncbi.nlm.nih.gov/pubmed/34745519 http://dx.doi.org/10.1039/d1sc04011a |
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