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Probing the electronic and mechanistic roles of the μ(4)-sulfur atom in a synthetic Cu(Z) model system

Nitrous oxide (N(2)O) contributes significantly to ozone layer depletion and is a potent greenhouse agent, motivating interest in the chemical details of biological N(2)O fixation by nitrous oxide reductase (N(2)OR) during bacterial denitrification. In this study, we report a combined experimental/c...

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Detalles Bibliográficos
Autores principales: Rathnayaka, Suresh C., Islam, Shahidul M., DiMucci, Ida M., MacMillan, Samantha N., Lancaster, Kyle M., Mankad, Neal P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8515425/
https://www.ncbi.nlm.nih.gov/pubmed/34745516
http://dx.doi.org/10.1039/c9sc06251c