Regio‐ and Stereoselective 1,2‐Carboboration of Ynamides with Aryldichloroboranes

Catalyst‐free 1,2‐carboboration of ynamides is presented. Readily available aryldichloroboranes react with alkyl‐ or aryl‐substituted ynamides in high yields with complete regio‐ and stereoselectivity to valuable β‐boryl‐β‐alkyl/aryl α‐aryl substituted enamides which belong to the class of trisubsti...

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Detalles Bibliográficos
Autores principales: You, Cai, Sakai, Mika, Daniliuc, Constantin G., Bergander, Klaus, Yamaguchi, Shigehiro, Studer, Armido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518048/
https://www.ncbi.nlm.nih.gov/pubmed/34310824
http://dx.doi.org/10.1002/anie.202107647

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518048/
https://www.ncbi.nlm.nih.gov/pubmed/34310824
http://dx.doi.org/10.1002/anie.202107647

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