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Regio‐ and Stereoselective 1,2‐Carboboration of Ynamides with Aryldichloroboranes
Catalyst‐free 1,2‐carboboration of ynamides is presented. Readily available aryldichloroboranes react with alkyl‐ or aryl‐substituted ynamides in high yields with complete regio‐ and stereoselectivity to valuable β‐boryl‐β‐alkyl/aryl α‐aryl substituted enamides which belong to the class of trisubsti...
Autores principales: | You, Cai, Sakai, Mika, Daniliuc, Constantin G., Bergander, Klaus, Yamaguchi, Shigehiro, Studer, Armido |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518048/ https://www.ncbi.nlm.nih.gov/pubmed/34310824 http://dx.doi.org/10.1002/anie.202107647 |
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