Radical Trifluoroacetylation of Alkenes Triggered by a Visible‐Light‐Promoted C–O Bond Fragmentation of Trifluoroacetic Anhydride

We report a mild and operationally simple trifluoroacylation strategy of olefines, that utilizes trifluoroacetic anhydride as a low‐cost and readily available reagent. This light‐mediated process is fundamentally different from conventional methodologies and occurs through a trifluoroacyl radical me...

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Detalles Bibliográficos
Autores principales: Zhang, Kun, Rombach, David, Nötel, Nicolas Yannick, Jeschke, Gunnar, Katayev, Dmitry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518413/
https://www.ncbi.nlm.nih.gov/pubmed/34289531
http://dx.doi.org/10.1002/anie.202109235

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518413/
https://www.ncbi.nlm.nih.gov/pubmed/34289531
http://dx.doi.org/10.1002/anie.202109235

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