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Type‐II Clathrate Na(24‐δ )Ge(136) from a Redox‐Preparation Route

The metastable type‐II clathrate Na(24‐δ )Ge(136) was obtained from Na(12)Ge(17) by applying a two‐step procedure. At first, Na(12)Ge(17) was reacted at 70 °C with a solution of benzophenone in the ionic liquid (IL) 1,3‐dibutyl‐2‐methylimidazolium‐bis(trifluoromethylsulfonyl) azanide. The IL was ine...

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Detalles Bibliográficos
Autores principales: Feng, Xian‐Juan, Bobnar, Matej, Lerch, Swantje, Biller, Harry, Schmidt, Marcus, Baitinger, Michael, Strassner, Thomas, Grin, Yuri, Böhme, Bodo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518416/
https://www.ncbi.nlm.nih.gov/pubmed/34270132
http://dx.doi.org/10.1002/chem.202102082