Cargando…

Catalyst Deactivation During Rhodium Complex‐Catalyzed Propargylic C−H Activation

Detailed mechanistic investigations on our previously reported synthesis of branched allylic esters by the rhodium complex‐catalyzed propargylic C−H activation have been carried out. Based on initial mechanistic studies, we present herein more detailed investigations of the reaction mechanism. For t...

Descripción completa

Detalles Bibliográficos
Autores principales:	Möller, Saskia, Jannsen, Nora, Rüger, Julia, Drexler, Hans‐Joachim, Horstmann, Moritz, Bauer, Felix, Breit, Bernhard, Heller, Detlef
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518492/ https://www.ncbi.nlm.nih.gov/pubmed/34260787 http://dx.doi.org/10.1002/chem.202102219

Ejemplares similares

Synthesis of Sulfoximine Propargyl Carbamates under Improved Conditions for Rhodium Catalyzed Carbamate Transfer to Sulfoxides
por: Zhong, Zhenhao, et al.
Publicado: (2022)

Rhodium-catalyzed asymmetric intramolecular hydroarylation of allenes: access to functionalized benzocycles
por: Berthold, Dino, et al.
Publicado: (2019)

A rhodium catalyzed cycloisomerization and tandem Diels–Alder reaction for facile access to diverse bicyclic and tricyclic heterocycles
por: Zhou, Yirong, et al.
Publicado: (2019)

Triaminocyclopentadienyl Ruthenium Complexes – New Catalysts for Cascade Conversions of Propargyl Alcohols
por: Hatzfeld, Jana, et al.
Publicado: (2021)

Rhodium‐Catalyzed Cyclization of Terminal and Internal Allenols: An Atom Economic and Highly Stereoselective Access Towards Tetrahydropyrans
por: Schmidt, Johannes P., et al.
Publicado: (2020)

Rhodium-catalyzed reductive carbonylation of aryl iodides to arylaldehydes with syngas
por: Liu, Zhenghui, et al.
Publicado: (2020)

Bis‐Cyclometalated Indazole Chiral‐at‐Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations
por: Steinlandt, Philipp S., et al.
Publicado: (2019)

Cu-catalyzed, Mn-mediated propargylation and allenylation of aldehydes with propargyl bromides
por: Zhang, Rongli, et al.
Publicado: (2022)

Rational Optimization of Supramolecular Catalysts for the Rhodium‐Catalyzed Asymmetric Hydrogenation Reaction
por: Daubignard, Julien, et al.
Publicado: (2017)

Ligand‐Mediated Regioselective Rhodium‐Catalyzed Benzotriazole–Allene Coupling: Mechanistic Exploration and Quantum Chemical Analysis
por: Sergeieva, Tetiana, et al.
Publicado: (2020)

Size‐Selective Hydroformylation by a Rhodium Catalyst Confined in a Supramolecular Cage
por: Nurttila, Sandra S., et al.
Publicado: (2018)

Asymmetric Hydroformylation Using a Rhodium Catalyst Encapsulated in a Chiral Capsule
por: Jongkind, Lukas J., et al.
Publicado: (2020)

Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes
por: Miura, Tomoya, et al.
Publicado: (2011)

Catalyst deactivation /
Publicado: (1999)

Overcoming naphthoquinone deactivation: rhodium-catalyzed C-5 selective C–H iodination as a gateway to functionalized derivatives
por: Jardim, Guilherme A. M., et al.
Publicado: (2016)

On the Reaction Mechanism of the Rhodium‐Catalyzed Arylation of Fullerene (C(60)) with Organoboron Compounds in the Presence of Water
por: Martínez, Juan Pablo, et al.
Publicado: (2015)

Expanded Ring NHC Silver Carboxylate Complexes as Efficient and Reusable Catalysts for the Carboxylative Cyclization of Unsubstituted Propargylic Derivatives
por: Cervantes‐Reyes, Alejandro, et al.
Publicado: (2021)

(+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate
por: Meissner, Antje, et al.
Publicado: (2012)

Photoredox cobalt-catalyzed regio-, diastereo- and enantioselective propargylation of aldehydes via propargyl radicals
por: Wang, Lei, et al.
Publicado: (2023)

Why base-catalyzed isomerization of N-propargyl amides yields mostly allenamides rather than ynamides
por: Navarro-Vázquez, Armando
Publicado: (2015)

(+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ(2) P,P′}(η(4)-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate
por: Schulz, Stefan, et al.
Publicado: (2010)

(+)-{1,2-Bis[(2R,5R)-2,5-diethylphospholan-1-yl]ethane-κ (2) P,P′}(η (4)-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate
por: Schulz, Stefan, et al.
Publicado: (2010)

Effect of Propargylic Substituents on Enantioselectivity and Reactivity in Ruthenium-Catalyzed Propargylic Substitution Reactions: A DFT Study
por: Sakata, Ken, et al.
Publicado: (2022)

Gold-catalyzed propargylic substitutions: Scope and synthetic developments
por: Debleds, Olivier, et al.
Publicado: (2011)

Gold‐Catalyzed Intramolecular Cyclizations of Cyclopropenes with Propargylic Esters
por: Zhu, Peng‐Long, et al.
Publicado: (2015)

Silver-Catalyzed Enantioselective Propargylation Reactions of N-Sulfonylketimines
por: Osborne, Charlotte A., et al.
Publicado: (2015)

HBF(4)-Catalysed Nucleophilic Substitutions of Propargylic Alcohols
por: Barreiro, Elena, et al.
Publicado: (2015)

Gold-catalyzed regioselective oxidation of propargylic carboxylates: a reliable access to α-carboxy-α,β-unsaturated ketones/aldehydes
por: Ji, Kegong, et al.
Publicado: (2013)

Sulfoxide-Directed Metal-Free ortho-Propargylation of Aromatics and Heteroaromatics
por: Eberhart, Andrew J, et al.
Publicado: (2015)

Combining the Ugi-azide multicomponent reaction and rhodium(III)-catalyzed annulation for the synthesis of tetrazole-isoquinolone/pyridone hybrids
por: Ojeda, Gerardo M, et al.
Publicado: (2019)

Rhodium-catalyzed intramolecular reductive aldol-type cyclization: Application for the synthesis of a chiral necic acid lactone
por: Isoda, Motoyuki, et al.
Publicado: (2022)

Tunable Gold‐catalyzed Reactions of Propargyl Alcohols and Aryl Nucleophiles
por: Jónsson, Helgi Freyr, et al.
Publicado: (2022)

Iron‐Catalyzed Borylation of Propargylic Acetates for the Synthesis of Multisubstituted Allenylboronates
por: Bermejo‐López, Aitor, et al.
Publicado: (2022)

Copper-catalyzed propargylic C–H functionalization for allene syntheses
por: Zhang, Dongjie, et al.
Publicado: (2023)

Rhodium(iii) catalyzed olefination and deuteration of tetrahydrocarbazole
por: Peng, Wan, et al.
Publicado: (2021)

Rhodium-catalyzed selenylation and sulfenylation of quinoxalinones ‘on water’
por: Lalji, Ram Sunil Kumar, et al.
Publicado: (2023)

Atom-Efficient Gold(I)-Chloride-Catalyzed Synthesis of α-Sulfenylated Carbonyl Compounds from Propargylic Alcohols and Aryl Thiols: Substrate Scope and Experimental and Theoretical Mechanistic Investigation
por: Biswas, Srijit, et al.
Publicado: (2013)

Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation
por: Schley, Nathan D., et al.
Publicado: (2014)

Regioselective Dihalohydration Reactions of Propargylic Alcohols: Gold-Catalyzed and Noncatalyzed Reactions**
por: D’Oyley, Jarryl M, et al.
Publicado: (2014)

A New Process for Efficient Recovery of Rhodium from Spent Carbonyl Rhodium Catalyst by Microreactor
por: Guo, Lei, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_5tc8l2kbd1orm1t6amvl6dcrm4