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A Neutral Beryllium(I) Radical

The reduction of a cyclic alkyl(amino)carbene (CAAC)‐stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, and UV/Vis spectroscopy, X‐ray crystallography, and DFT calculations.

Detalles Bibliográficos
Autores principales: Czernetzki, Corinna, Arrowsmith, Merle, Fantuzzi, Felipe, Gärtner, Annalena, Tröster, Tobias, Krummenacher, Ivo, Schorr, Fabian, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518760/
https://www.ncbi.nlm.nih.gov/pubmed/34263524
http://dx.doi.org/10.1002/anie.202108405
Descripción
Sumario:The reduction of a cyclic alkyl(amino)carbene (CAAC)‐stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, and UV/Vis spectroscopy, X‐ray crystallography, and DFT calculations.