Cargando…

A Neutral Beryllium(I) Radical

The reduction of a cyclic alkyl(amino)carbene (CAAC)‐stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, and UV/Vis spectroscopy, X‐ray crystallography, and DFT calculations.

Detalles Bibliográficos
Autores principales: Czernetzki, Corinna, Arrowsmith, Merle, Fantuzzi, Felipe, Gärtner, Annalena, Tröster, Tobias, Krummenacher, Ivo, Schorr, Fabian, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518760/
https://www.ncbi.nlm.nih.gov/pubmed/34263524
http://dx.doi.org/10.1002/anie.202108405
_version_ 1784584299403542528
author Czernetzki, Corinna
Arrowsmith, Merle
Fantuzzi, Felipe
Gärtner, Annalena
Tröster, Tobias
Krummenacher, Ivo
Schorr, Fabian
Braunschweig, Holger
author_facet Czernetzki, Corinna
Arrowsmith, Merle
Fantuzzi, Felipe
Gärtner, Annalena
Tröster, Tobias
Krummenacher, Ivo
Schorr, Fabian
Braunschweig, Holger
author_sort Czernetzki, Corinna
collection PubMed
description The reduction of a cyclic alkyl(amino)carbene (CAAC)‐stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, and UV/Vis spectroscopy, X‐ray crystallography, and DFT calculations.
format Online
Article
Text
id pubmed-8518760
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-85187602021-10-21 A Neutral Beryllium(I) Radical Czernetzki, Corinna Arrowsmith, Merle Fantuzzi, Felipe Gärtner, Annalena Tröster, Tobias Krummenacher, Ivo Schorr, Fabian Braunschweig, Holger Angew Chem Int Ed Engl Communications The reduction of a cyclic alkyl(amino)carbene (CAAC)‐stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, and UV/Vis spectroscopy, X‐ray crystallography, and DFT calculations. John Wiley and Sons Inc. 2021-08-24 2021-09-13 /pmc/articles/PMC8518760/ /pubmed/34263524 http://dx.doi.org/10.1002/anie.202108405 Text en © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Czernetzki, Corinna
Arrowsmith, Merle
Fantuzzi, Felipe
Gärtner, Annalena
Tröster, Tobias
Krummenacher, Ivo
Schorr, Fabian
Braunschweig, Holger
A Neutral Beryllium(I) Radical
title A Neutral Beryllium(I) Radical
title_full A Neutral Beryllium(I) Radical
title_fullStr A Neutral Beryllium(I) Radical
title_full_unstemmed A Neutral Beryllium(I) Radical
title_short A Neutral Beryllium(I) Radical
title_sort neutral beryllium(i) radical
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518760/
https://www.ncbi.nlm.nih.gov/pubmed/34263524
http://dx.doi.org/10.1002/anie.202108405
work_keys_str_mv AT czernetzkicorinna aneutralberylliumiradical
AT arrowsmithmerle aneutralberylliumiradical
AT fantuzzifelipe aneutralberylliumiradical
AT gartnerannalena aneutralberylliumiradical
AT trostertobias aneutralberylliumiradical
AT krummenacherivo aneutralberylliumiradical
AT schorrfabian aneutralberylliumiradical
AT braunschweigholger aneutralberylliumiradical
AT czernetzkicorinna neutralberylliumiradical
AT arrowsmithmerle neutralberylliumiradical
AT fantuzzifelipe neutralberylliumiradical
AT gartnerannalena neutralberylliumiradical
AT trostertobias neutralberylliumiradical
AT krummenacherivo neutralberylliumiradical
AT schorrfabian neutralberylliumiradical
AT braunschweigholger neutralberylliumiradical