Polymorphic Phosphorescence from Separable Aggregates with Unique Photophysical Properties

Platinum complexes aggregate into polymorphs with different intermolecular interactions leading to different photophysical properties. Strong intermolecular interactions stabilize the aggregate to such an extent that the polymorphs can be separated directly by column chromatography. Solid‐state stru...

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Detalles Bibliográficos
Autores principales: Pinter, Piermaria, Hennersdorf, Felix, Weigand, Jan J., Strassner, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518788/
https://www.ncbi.nlm.nih.gov/pubmed/34405914
http://dx.doi.org/10.1002/chem.202100483
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author Pinter, Piermaria
Hennersdorf, Felix
Weigand, Jan J.
Strassner, Thomas
author_facet Pinter, Piermaria
Hennersdorf, Felix
Weigand, Jan J.
Strassner, Thomas
author_sort Pinter, Piermaria
collection PubMed
description Platinum complexes aggregate into polymorphs with different intermolecular interactions leading to different photophysical properties. Strong intermolecular interactions stabilize the aggregate to such an extent that the polymorphs can be separated directly by column chromatography. Solid‐state structures as well as quantum‐chemical calculations confirmed the effect of the interactions on the photophysical properties.
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spelling pubmed-85187882021-10-21 Polymorphic Phosphorescence from Separable Aggregates with Unique Photophysical Properties Pinter, Piermaria Hennersdorf, Felix Weigand, Jan J. Strassner, Thomas Chemistry Communications Platinum complexes aggregate into polymorphs with different intermolecular interactions leading to different photophysical properties. Strong intermolecular interactions stabilize the aggregate to such an extent that the polymorphs can be separated directly by column chromatography. Solid‐state structures as well as quantum‐chemical calculations confirmed the effect of the interactions on the photophysical properties. John Wiley and Sons Inc. 2021-08-18 2021-09-15 /pmc/articles/PMC8518788/ /pubmed/34405914 http://dx.doi.org/10.1002/chem.202100483 Text en © 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Pinter, Piermaria
Hennersdorf, Felix
Weigand, Jan J.
Strassner, Thomas
Polymorphic Phosphorescence from Separable Aggregates with Unique Photophysical Properties
title Polymorphic Phosphorescence from Separable Aggregates with Unique Photophysical Properties
title_full Polymorphic Phosphorescence from Separable Aggregates with Unique Photophysical Properties
title_fullStr Polymorphic Phosphorescence from Separable Aggregates with Unique Photophysical Properties
title_full_unstemmed Polymorphic Phosphorescence from Separable Aggregates with Unique Photophysical Properties
title_short Polymorphic Phosphorescence from Separable Aggregates with Unique Photophysical Properties
title_sort polymorphic phosphorescence from separable aggregates with unique photophysical properties
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518788/
https://www.ncbi.nlm.nih.gov/pubmed/34405914
http://dx.doi.org/10.1002/chem.202100483
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AT hennersdorffelix polymorphicphosphorescencefromseparableaggregateswithuniquephotophysicalproperties
AT weigandjanj polymorphicphosphorescencefromseparableaggregateswithuniquephotophysicalproperties
AT strassnerthomas polymorphicphosphorescencefromseparableaggregateswithuniquephotophysicalproperties

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