Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations

Herein, we disclose a recyclable, hybrid manganese catalyst for site‐selective azine C−H activation by weak amide assistance. The novel, reusable catalyst enabled C3–H arylation and C3–H alkylation with ample scope, and was characterized by detailed transmission electron microscopy analysis.

Detalles Bibliográficos
Autores principales: Choi, Isaac, Shen, Zhigao, Ronge, Emanuel, Karius, Volker, Jooss, Christian, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518803/
https://www.ncbi.nlm.nih.gov/pubmed/34181789
http://dx.doi.org/10.1002/chem.202101894
Descripción
Sumario:Herein, we disclose a recyclable, hybrid manganese catalyst for site‐selective azine C−H activation by weak amide assistance. The novel, reusable catalyst enabled C3–H arylation and C3–H alkylation with ample scope, and was characterized by detailed transmission electron microscopy analysis.

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