Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations

Herein, we disclose a recyclable, hybrid manganese catalyst for site‐selective azine C−H activation by weak amide assistance. The novel, reusable catalyst enabled C3–H arylation and C3–H alkylation with ample scope, and was characterized by detailed transmission electron microscopy analysis.

Detalles Bibliográficos
Autores principales: Choi, Isaac, Shen, Zhigao, Ronge, Emanuel, Karius, Volker, Jooss, Christian, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518803/
https://www.ncbi.nlm.nih.gov/pubmed/34181789
http://dx.doi.org/10.1002/chem.202101894
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author Choi, Isaac
Shen, Zhigao
Ronge, Emanuel
Karius, Volker
Jooss, Christian
Ackermann, Lutz
author_facet Choi, Isaac
Shen, Zhigao
Ronge, Emanuel
Karius, Volker
Jooss, Christian
Ackermann, Lutz
author_sort Choi, Isaac
collection PubMed
description Herein, we disclose a recyclable, hybrid manganese catalyst for site‐selective azine C−H activation by weak amide assistance. The novel, reusable catalyst enabled C3–H arylation and C3–H alkylation with ample scope, and was characterized by detailed transmission electron microscopy analysis.
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spelling pubmed-85188032021-10-21 Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations Choi, Isaac Shen, Zhigao Ronge, Emanuel Karius, Volker Jooss, Christian Ackermann, Lutz Chemistry Communications Herein, we disclose a recyclable, hybrid manganese catalyst for site‐selective azine C−H activation by weak amide assistance. The novel, reusable catalyst enabled C3–H arylation and C3–H alkylation with ample scope, and was characterized by detailed transmission electron microscopy analysis. John Wiley and Sons Inc. 2021-07-29 2021-09-06 /pmc/articles/PMC8518803/ /pubmed/34181789 http://dx.doi.org/10.1002/chem.202101894 Text en © 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ (https://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Choi, Isaac
Shen, Zhigao
Ronge, Emanuel
Karius, Volker
Jooss, Christian
Ackermann, Lutz
Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations
title Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations
title_full Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations
title_fullStr Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations
title_full_unstemmed Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations
title_short Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations
title_sort reusable manganese catalyst for site‐selective pyridine c−h arylations and alkylations
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518803/
https://www.ncbi.nlm.nih.gov/pubmed/34181789
http://dx.doi.org/10.1002/chem.202101894
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