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Origin of the α‐Effect in S(N)2 Reactions
The α‐effect is a term used to explain the dramatically enhanced reactivity of α‐nucleophiles (R−Y−X:(−)) compared to their parent normal nucleophile (R−X:(−)) by deviating from the classical Brønsted‐type reactivity‐basicity relationship. The exact origin of this effect is, however, still heavily u...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518820/ https://www.ncbi.nlm.nih.gov/pubmed/34087047 http://dx.doi.org/10.1002/anie.202106053 |