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Inorganic Synthesis Based on Reactions of Ionic Liquids and Deep Eutectic Solvents

Ionic liquids and deep eutectic solvents are of growing interest as solvents for the resource‐efficient synthesis of inorganic materials. This Review covers chemical reactions of various deep eutectic solvents and types of ionic liquids, including metal‐containing ionic liquids, [BF(4)](−)‐ or [PF(6...

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Detalles Bibliográficos
Autores principales: Zhang, Tao, Doert, Thomas, Wang, Hui, Zhang, Suojiang, Ruck, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518931/
https://www.ncbi.nlm.nih.gov/pubmed/34032351
http://dx.doi.org/10.1002/anie.202104035
Descripción
Sumario:Ionic liquids and deep eutectic solvents are of growing interest as solvents for the resource‐efficient synthesis of inorganic materials. This Review covers chemical reactions of various deep eutectic solvents and types of ionic liquids, including metal‐containing ionic liquids, [BF(4)](−)‐ or [PF(6)](−)‐based ionic liquids, basic ionic liquids, and chalcogen‐containing ionic liquids. Cases in which cations, anions, or both are incorporated into the final products are also included. The purpose of this Review is to raise caution about the chemical reactivity of ionic liquids and deep eutectic solvents and to establish a guide for their proper use.