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Carbonyl Hypoiodites as Extremely Strong Halogen Bond Donors

Neutral halogen‐bonded O−I−N complexes were prepared from in situ formed carbonyl hypoiodites and aromatic organic bases. The carbonyl hypoiodites have a strongly polarized iodine atom with larger σ‐holes than any known uncharged halogen bond donor. Modulating the Lewis basicity of the selected pyri...

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Detalles Bibliográficos
Autores principales:	Yu, Shilin, Ward, Jas S., Truong, Khai‐Nghi, Rissanen, Kari
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518949/ https://www.ncbi.nlm.nih.gov/pubmed/34268851 http://dx.doi.org/10.1002/anie.202108126

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