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Palladium‐Catalyzed Cascade Carbonylation to α,β‐Unsaturated Piperidones via Selective Cleavage of Carbon–Carbon Triple Bonds
A direct and selective synthesis of α,β‐unsaturated piperidones by a new palladium‐catalyzed cascade carbonylation is described. In the presented protocol, easily available propargylic alcohols react with aliphatic amines to provide a broad variety of interesting heterocycles. Key to the success of...
Autores principales: | Ge, Yao, Ye, Fei, Yang, Ji, Spannenberg, Anke, Jiao, Haijun, Jackstell, Ralf, Beller, Matthias |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519052/ https://www.ncbi.nlm.nih.gov/pubmed/34382728 http://dx.doi.org/10.1002/anie.202108120 |
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