Cargando…

Catalytic Formal Hydroamination of Allylic Alcohols Using Manganese PNP‐Pincer Complexes

Several manganese‐PNP pincer catalysts for the formal hydroamination of allylic alcohols are presented. The resulting γ‐amino alcohols are selectively obtained in high yields applying Mn‐1 in a tandem process under mild conditions. [Image: see text]

Detalles Bibliográficos
Autores principales:	Duarte de Almeida, Leandro, Bourriquen, Florian, Junge, Kathrin, Beller, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519145/ https://www.ncbi.nlm.nih.gov/pubmed/34690626 http://dx.doi.org/10.1002/adsc.202100081

Ejemplares similares

Low-Valent Molybdenum PNP Pincer Complexes as Catalysts for the Semihydrogenation of Alkynes
por: Both, Niklas F., et al.
Publicado: (2022)

Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes
por: Elangovan, Saravanakumar, et al.
Publicado: (2016)

Manganese‐Catalysed Deuterium Labelling of Anilines and Electron‐Rich (Hetero)Arenes
por: Bourriquen, Florian, et al.
Publicado: (2022)

Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese–PNN pincer complex
por: Papa, Veronica, et al.
Publicado: (2017)

A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol
por: Andérez‐Fernández, María, et al.
Publicado: (2016)

Non‐Pincer‐Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters
por: van Putten, Robbert, et al.
Publicado: (2017)

HCOOH disproportionation to MeOH promoted by molybdenum PNP complexes
por: Alberico, Elisabetta, et al.
Publicado: (2021)

Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation
por: Kuriyama, Shogo, et al.
Publicado: (2022)

Synthesis and Characterization of Hydrido Carbonyl Molybdenum and Tungsten PNP Pincer Complexes
por: Öztopcu, Özgür, et al.
Publicado: (2013)

Correction: HCOOH disproportionation to MeOH promoted by molybdenum PNP complexes
por: Alberico, Elisabetta, et al.
Publicado: (2021)

Structural and Electronic Properties of Iron(0) PNP Pincer Complexes
por: Glatz, Mathias, et al.
Publicado: (2021)

Sustainable catalysis with fluxional acridine-based PNP pincer complexes
por: Kar, Sayan, et al.
Publicado: (2022)

Efficient Hydrogenation of N‐Heterocycles Catalyzed by NNP–Manganese(I) Pincer Complexes at Ambient Temperature
por: Papa, Veronica, et al.
Publicado: (2022)

Recent Advances in Catalytic Hydrosilylations: Developments beyond Traditional Platinum Catalysts
por: de Almeida, Leandro Duarte, et al.
Publicado: (2020)

Cyclometalated Ruthenium Pincer Complexes as Catalysts for the α‐Alkylation of Ketones with Alcohols
por: Piehl, Patrick, et al.
Publicado: (2020)

Synthesis and characterization of cationic dicarbonyl Fe(II) PNP pincer complexes
por: Glatz, Mathias, et al.
Publicado: (2016)

Electrocatalytic Azide Oxidation Mediated by a Rh(PNP) Pincer Complex
por: Rebreyend, Christophe, et al.
Publicado: (2017)

Synthesis, structure and π-delocalization of a phosphaalkenyl based neutral PNP-pincer
por: Orthaber, Andreas, et al.
Publicado: (2011)

Synthesis and reactivity of BINEPINE-based chiral Fe(II) PNP pincer complexes
por: Schröder-Holzhacker, Christian, et al.
Publicado: (2016)

Asymmetric synthesis of allylic amines via hydroamination of allenes with benzophenone imine
por: Xu, Kun, et al.
Publicado: (2016)

Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism
por: Leischner, Thomas, et al.
Publicado: (2019)

Structural diversity of halocarbonyl molybdenum and tungsten PNP pincer complexes through ligand modifications
por: de Aguiar, Sara R. M. M., et al.
Publicado: (2016)

Synthesis and characterization of TADDOL-based chiral group six PNP pincer tricarbonyl complexes
por: de Aguiar, Sara R. M. M., et al.
Publicado: (2018)

Preparation of a Series of Supported Nonsymmetrical PNP‐Pincer Ligands and the Application in Ester Hydrogenation
por: Konrath, Robert, et al.
Publicado: (2019)

The Mechanism of Markovnikov-Selective Epoxide Hydrogenolysis Catalyzed by Ruthenium PNN and PNP Pincer Complexes
por: Head, Marianna C., et al.
Publicado: (2023)

Synthesis of (+)-ribostamycin by catalytic, enantioselective hydroamination of benzene
por: Ungarean, Chad N., et al.
Publicado: (2022)

Formation of Mono Oxo Molybdenum(IV) PNP Pincer Complexes: Interplay between Water and Molecular Oxygen
por: de Aguiar, Sara R. M. M., et al.
Publicado: (2018)

Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal–Ligand Cooperation
por: Bichler, Bernhard, et al.
Publicado: (2013)

Synthesis and characterization of bis- and tris-carbonyl Mn(I) and Re(I) PNP pincer complexes
por: Glatz, Mathias, et al.
Publicado: (2018)

Carbon dioxide hydrogenation catalysed by well-defined Mn(i) PNP pincer hydride complexes
por: Bertini, Federica, et al.
Publicado: (2017)

Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex
por: Bézier, David, et al.
Publicado: (2016)

Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes
por: Hood, Thomas M., et al.
Publicado: (2019)

DFT calculations bring insight to internal alkyne-to-vinylidene transformations at rhodium PNP- and PONOP-pincer complexes
por: Rajabi, Nasir A., et al.
Publicado: (2021)

Copper-catalysed low-temperature water–gas shift reaction for selective deuteration of aryl halides
por: Li, Wu, et al.
Publicado: (2021)

Selective Hydrogenation of Aldehydes Using a Well‐Defined Fe(II) PNP Pincer Complex in Biphasic Medium
por: Weber, Stefan, et al.
Publicado: (2018)

Copper(II)-Catalyzed Three-Component Arylation/Hydroamination Cascade from Allyl Alcohol: Access to 1-Aryl-2-sulfonylamino-propanes
por: Loro, Camilla, et al.
Publicado: (2023)

A triazine-based Ni(II) PNP pincer complex as catalyst for Kumada–Corriu and Negishi cross-coupling reactions
por: Mastalir, Mathias, et al.
Publicado: (2016)

Efficient Hydrogenation of Ketones and Aldehydes Catalyzed by Well-Defined Iron(II) PNP Pincer Complexes: Evidence for an Insertion Mechanism
por: Gorgas, Nikolaus, et al.
Publicado: (2014)

Pyrrole-Based Ti(III) and Ti(IV) PNP Pincer Complexes: Insertion of Ketones into the Ti(IV)-Phosphorus Bond
por: Tomsu, Gerald, et al.
Publicado: (2023)

Ligand survey results in identification of PNP pincer complexes of iridium as long-lived and chemoselective catalysts for dehydrogenative borylation of terminal alkynes
por: Lee, Chun-I, et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_34dnu92vajptg0n4i2qrv841eg