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Discovery and Implications of Hidden Atomic-Scale Structure in a Metallic Meteorite

[Image: see text] Iron and its alloys have made modern civilization possible, with metallic meteorites providing one of the human’s earliest sources of usable iron as well as providing a window into our solar system’s billion-year history. Here highest-resolution tools reveal the existence of a prev...

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Autores principales: Kovács, András, Lewis, Laura H., Palanisamy, Dhanalaksmi, Denneulin, Thibaud, Schwedt, Alexander, Scott, Edward R.D., Gault, Baptiste, Raabe, Dierk, Dunin-Borkowski, Rafal E., Charilaou, Michalis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519181/
https://www.ncbi.nlm.nih.gov/pubmed/34529916
http://dx.doi.org/10.1021/acs.nanolett.1c02573
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author Kovács, András
Lewis, Laura H.
Palanisamy, Dhanalaksmi
Denneulin, Thibaud
Schwedt, Alexander
Scott, Edward R.D.
Gault, Baptiste
Raabe, Dierk
Dunin-Borkowski, Rafal E.
Charilaou, Michalis
author_facet Kovács, András
Lewis, Laura H.
Palanisamy, Dhanalaksmi
Denneulin, Thibaud
Schwedt, Alexander
Scott, Edward R.D.
Gault, Baptiste
Raabe, Dierk
Dunin-Borkowski, Rafal E.
Charilaou, Michalis
author_sort Kovács, András
collection PubMed
description [Image: see text] Iron and its alloys have made modern civilization possible, with metallic meteorites providing one of the human’s earliest sources of usable iron as well as providing a window into our solar system’s billion-year history. Here highest-resolution tools reveal the existence of a previously hidden FeNi nanophase within the extremely slowly cooled metallic meteorite NWA 6259. This new nanophase exists alongside Ni-poor and Ni-rich nanoprecipitates within a matrix of tetrataenite, the uniaxial, chemically ordered form of FeNi. The ferromagnetic nature of the nanoprecipitates combined with the antiferromagnetic character of the FeNi nanophases gives rise to a complex magnetic state that evolves dramatically with temperature. These observations extend and possibly alter our understanding of celestial metallurgy, provide new knowledge concerning the archetypal Fe–Ni phase diagram and supply new information for the development of new types of sustainable, technologically critical high-energy magnets.
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spelling pubmed-85191812022-09-16 Discovery and Implications of Hidden Atomic-Scale Structure in a Metallic Meteorite Kovács, András Lewis, Laura H. Palanisamy, Dhanalaksmi Denneulin, Thibaud Schwedt, Alexander Scott, Edward R.D. Gault, Baptiste Raabe, Dierk Dunin-Borkowski, Rafal E. Charilaou, Michalis Nano Lett [Image: see text] Iron and its alloys have made modern civilization possible, with metallic meteorites providing one of the human’s earliest sources of usable iron as well as providing a window into our solar system’s billion-year history. Here highest-resolution tools reveal the existence of a previously hidden FeNi nanophase within the extremely slowly cooled metallic meteorite NWA 6259. This new nanophase exists alongside Ni-poor and Ni-rich nanoprecipitates within a matrix of tetrataenite, the uniaxial, chemically ordered form of FeNi. The ferromagnetic nature of the nanoprecipitates combined with the antiferromagnetic character of the FeNi nanophases gives rise to a complex magnetic state that evolves dramatically with temperature. These observations extend and possibly alter our understanding of celestial metallurgy, provide new knowledge concerning the archetypal Fe–Ni phase diagram and supply new information for the development of new types of sustainable, technologically critical high-energy magnets. American Chemical Society 2021-09-16 2021-10-13 /pmc/articles/PMC8519181/ /pubmed/34529916 http://dx.doi.org/10.1021/acs.nanolett.1c02573 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Kovács, András
Lewis, Laura H.
Palanisamy, Dhanalaksmi
Denneulin, Thibaud
Schwedt, Alexander
Scott, Edward R.D.
Gault, Baptiste
Raabe, Dierk
Dunin-Borkowski, Rafal E.
Charilaou, Michalis
Discovery and Implications of Hidden Atomic-Scale Structure in a Metallic Meteorite
title Discovery and Implications of Hidden Atomic-Scale Structure in a Metallic Meteorite
title_full Discovery and Implications of Hidden Atomic-Scale Structure in a Metallic Meteorite
title_fullStr Discovery and Implications of Hidden Atomic-Scale Structure in a Metallic Meteorite
title_full_unstemmed Discovery and Implications of Hidden Atomic-Scale Structure in a Metallic Meteorite
title_short Discovery and Implications of Hidden Atomic-Scale Structure in a Metallic Meteorite
title_sort discovery and implications of hidden atomic-scale structure in a metallic meteorite
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519181/
https://www.ncbi.nlm.nih.gov/pubmed/34529916
http://dx.doi.org/10.1021/acs.nanolett.1c02573
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