Direct conversion of CO(2) to a jet fuel over CoFe alloy catalysts

The direct conversion of carbon dioxide (CO(2)) using green hydrogen is a sustainable approach to jet fuel production. However, achieving a high level of performance remains a formidable challenge due to the inertness of CO(2) and its low activity for subsequent C–C bond formation. In this study, we prepared a Na-modified CoFe alloy catalyst using layered double-hydroxide precursors that directly transforms CO(2) to a jet fuel composed of C(8)–C(16) jet-fuel-range hydrocarbons with very high selectivity. At a temperature of 240°C and pressure of 3 MPa, the catalyst achieves an unprecedentedly high C(8)–C(16) selectivity of 63.5% with 10.2% CO(2) conversion and a low combined selectivity of less than 22% toward undesired CO and CH(4). Spectroscopic and computational studies show that the promotion of the coupling reaction between the carbon species and inhibition of the undesired CO(2) methanation occur mainly due to the utilization of the CoFe alloy structure and addition of the Na promoter. This study provides a viable technique for the highly selective synthesis of eco-friendly and carbon-neutral jet fuel from CO(2).