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Large-Scale Synthesis and Modifications of Bicyclo[1.1.1]pentane-1,3-dicarboxylic Acid (BCP)

[Image: see text] In flow photochemical addition of propellane to diacetyl allowed construction of the bicyclo[1.1.1]pentane (BCP) core in a 1 kg scale within 1 day. Haloform reaction of the formed diketone in batch afforded bicyclo[1.1.1]pentane-1,3-dicarboxylic acid in a multigram amount. Represen...

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Detalles Bibliográficos
Autores principales:	Ripenko, Vasyl, Vysochyn, Daniil, Klymov, Ivan, Zhersh, Serhii, Mykhailiuk, Pavel K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8524415/ https://www.ncbi.nlm.nih.gov/pubmed/34166594 http://dx.doi.org/10.1021/acs.joc.1c00977

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