Switchable Oxidative Reactions of N-allyl-2-Aminophenols: Palladium-Catalyzed Alkoxyacyloxylation vs an Intramolecular Diels–Alder Reaction

[Image: see text] The Pd(II)-catalyzed reaction of N-allyl-2-aminophenols in the presence of PhI(OCOR)(2) as the oxidant resulted in an alkoxyacyloxylation process, with the formation of functionalized dihydro-1,4-benzoxazines. The reaction performed in the absence of palladium catalyst switched to...

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Detalles Bibliográficos
Autores principales: Giofrè, Sabrina, Keller, Manfred, Lo Presti, Leonardo, Beccalli, Egle M., Molteni, Letizia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8524420/
https://www.ncbi.nlm.nih.gov/pubmed/34570517
http://dx.doi.org/10.1021/acs.orglett.1c02539

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8524420/
https://www.ncbi.nlm.nih.gov/pubmed/34570517
http://dx.doi.org/10.1021/acs.orglett.1c02539

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