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Environmental Remediation of Toxic Organic Pollutants Using Visible-Light-Activated Cu/La/CeO(2)/GO Nanocomposites

Environmental pollution is a major threat that increases day by day due to various activities. A wide variety of organic pollutants enter the environment due to petrochemical activities. Organic contamination can be unsafe, oncogenic, and lethal. Due to environmental issues worldwide, scientists and...

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Autores principales: Vasu, Dhanapal, Fu, Yongsheng, Keyan, Arjunan Karthi, Sakthinathan, Subramanian, Chiu, Te-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8537214/
https://www.ncbi.nlm.nih.gov/pubmed/34683735
http://dx.doi.org/10.3390/ma14206143
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author Vasu, Dhanapal
Fu, Yongsheng
Keyan, Arjunan Karthi
Sakthinathan, Subramanian
Chiu, Te-Wei
author_facet Vasu, Dhanapal
Fu, Yongsheng
Keyan, Arjunan Karthi
Sakthinathan, Subramanian
Chiu, Te-Wei
author_sort Vasu, Dhanapal
collection PubMed
description Environmental pollution is a major threat that increases day by day due to various activities. A wide variety of organic pollutants enter the environment due to petrochemical activities. Organic contamination can be unsafe, oncogenic, and lethal. Due to environmental issues worldwide, scientists and research communities are focusing their research efforts on this area. For the removal of toxic organic pollutants from the environment, photocatalysis-assisted degradation processes have gained more attention than other advanced oxidation processes (AOPs). In this manuscript, we report a novel photocatalysis of copper and lanthanum incorporating cerium oxide (CeO(2)) loaded on graphene oxide (Cu/La/CeO(2)/GO) nanocomposites successfully synthesized by hydrothermal techniques. XRD results showed the presence of dopant ions and a crystalline structure. FESEM images showed that the surface morphology of the synthesized nanocomposites formed a rod-like structure. The highlight of this study is the in-situ synthesis of the novel Cu/La/CeO(2)/GO nanocomposites, which manifest higher photodegradation of harmful organic dyes (Rhodamine B (RhB), Sunset Yellow (SY), and Cibacron Red (CR)). In Cu/La/CeO(2)/GO nanocomposites, the dopant materials restrict the rapid recombination of photoinduced electron–hole pairs and enhance the photocatalytic activity. The degradation percentages of RhB, SY, and CR dye solution are 80%, 60%, and 95%, respectively. In summary, the synthesized nanocomposites degrade toxic organic dyes with the help of visible light and are suitable for future industrial applications.
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spelling pubmed-85372142021-10-24 Environmental Remediation of Toxic Organic Pollutants Using Visible-Light-Activated Cu/La/CeO(2)/GO Nanocomposites Vasu, Dhanapal Fu, Yongsheng Keyan, Arjunan Karthi Sakthinathan, Subramanian Chiu, Te-Wei Materials (Basel) Article Environmental pollution is a major threat that increases day by day due to various activities. A wide variety of organic pollutants enter the environment due to petrochemical activities. Organic contamination can be unsafe, oncogenic, and lethal. Due to environmental issues worldwide, scientists and research communities are focusing their research efforts on this area. For the removal of toxic organic pollutants from the environment, photocatalysis-assisted degradation processes have gained more attention than other advanced oxidation processes (AOPs). In this manuscript, we report a novel photocatalysis of copper and lanthanum incorporating cerium oxide (CeO(2)) loaded on graphene oxide (Cu/La/CeO(2)/GO) nanocomposites successfully synthesized by hydrothermal techniques. XRD results showed the presence of dopant ions and a crystalline structure. FESEM images showed that the surface morphology of the synthesized nanocomposites formed a rod-like structure. The highlight of this study is the in-situ synthesis of the novel Cu/La/CeO(2)/GO nanocomposites, which manifest higher photodegradation of harmful organic dyes (Rhodamine B (RhB), Sunset Yellow (SY), and Cibacron Red (CR)). In Cu/La/CeO(2)/GO nanocomposites, the dopant materials restrict the rapid recombination of photoinduced electron–hole pairs and enhance the photocatalytic activity. The degradation percentages of RhB, SY, and CR dye solution are 80%, 60%, and 95%, respectively. In summary, the synthesized nanocomposites degrade toxic organic dyes with the help of visible light and are suitable for future industrial applications. MDPI 2021-10-16 /pmc/articles/PMC8537214/ /pubmed/34683735 http://dx.doi.org/10.3390/ma14206143 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Vasu, Dhanapal
Fu, Yongsheng
Keyan, Arjunan Karthi
Sakthinathan, Subramanian
Chiu, Te-Wei
Environmental Remediation of Toxic Organic Pollutants Using Visible-Light-Activated Cu/La/CeO(2)/GO Nanocomposites
title Environmental Remediation of Toxic Organic Pollutants Using Visible-Light-Activated Cu/La/CeO(2)/GO Nanocomposites
title_full Environmental Remediation of Toxic Organic Pollutants Using Visible-Light-Activated Cu/La/CeO(2)/GO Nanocomposites
title_fullStr Environmental Remediation of Toxic Organic Pollutants Using Visible-Light-Activated Cu/La/CeO(2)/GO Nanocomposites
title_full_unstemmed Environmental Remediation of Toxic Organic Pollutants Using Visible-Light-Activated Cu/La/CeO(2)/GO Nanocomposites
title_short Environmental Remediation of Toxic Organic Pollutants Using Visible-Light-Activated Cu/La/CeO(2)/GO Nanocomposites
title_sort environmental remediation of toxic organic pollutants using visible-light-activated cu/la/ceo(2)/go nanocomposites
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8537214/
https://www.ncbi.nlm.nih.gov/pubmed/34683735
http://dx.doi.org/10.3390/ma14206143
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