CVD Synthesis of Intermediate State-Free, Large-Area and Continuous MoS(2) via Single-Step Vapor-Phase Sulfurization of MoO(2) Precursor

The low evaporation temperature and carcinogen classification of commonly used molybdenum trioxide (MoO(3)) precursor render it unsuitable for the safe and practical synthesis of molybdenum disulfide (MoS(2)). Furthermore, as evidenced by several experimental findings, the associated reaction constitutes a multistep process prone to the formation of uncontrolled amounts of intermediate MoS(2−y)O(y) phase mixed with the MoS(2) crystals. Here, molybdenum dioxide (MoO(2)), a chemically more stable and safer oxide than MoO(3), was utilized to successfully grow cm-scale continuous films of monolayer MoS(2). A high-resolution optical image stitching approach and Raman line mapping were used to confirm the composition and homogeneity of the material grown across the substrate. A detailed examination of the surface morphology of the continuous film revealed that, as the gas flow rate increased by an order of magnitude, the grain-boundary separation dramatically reduced, implying a transition from a kinetically to thermodynamically controlled growth. Importantly, the single-step vapor-phase sulfurization (VPS) reaction of MoO(2) was shown to suppress intermediate state formations for a wide range of experimental parameters investigated and is completely absent, provided that the global S:Mo loading ratio is set higher than the stoichiometric ratio of 3:1 required by the VPS reaction.