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Spectroscopic Evidence for a Cobalt-Bound Peroxyhemiacetal Intermediate

[Image: see text] Aldehyde deformylation reactions by metal dioxygen adducts have been proposed to involve peroxyhemiacetal species as key intermediates. However, direct evidence of such intermediates has not been obtained to date. We report the spectroscopic characterization of a mononuclear cobalt...

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Detalles Bibliográficos
Autores principales:	Son, Yeongjin, Kim, Kyungmin, Kim, Seonghan, Tripodi, Guilherme L., Pereverzev, Aleksandr, Roithová, Jana, Cho, Jaeheung
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8549039/ https://www.ncbi.nlm.nih.gov/pubmed/34723262 http://dx.doi.org/10.1021/jacsau.1c00166

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